Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Rhenium part XV. Tetragonal complexes of nickel(II) containing coordinated perrhenate [ReO4]

  • 69 Accesses

  • 6 Citations

Summary

The compounds Ni(NH3)4(ReO4)2 and Ni(py)4(ReO4)2 prepared by reacting Ni(ReO4)2 with aqueous ammonia or pyridine, when heated at 150° give Ni(NH3)2(ReO4)2 and Ni(py)2(ReO4)2 respectively. The kinetics of the thermal decomposition of Ni(NH3)2(ReO4)2 has been studied. I.r., Raman and electronic spectra, x-ray powder diffraction and magnetic susceptibility measurements (at different temperatures) of the four compounds indicate that they are tetragonal complexes of NiII containing coordinated perrhenate.

This is a preview of subscription content, log in to check access.

References

  1. (17

    M. R. Rosenthal,J. Chem. Educ., 50, 331 (1973).

  2. (2)

    E. Lenz and R. K. Murmann,Inorg. Chem., 7, 1880 (1968).

  3. (3)

    S. H. Hunter, R. S. Nyholm and G. A. Rodley,Inorg. Chim. Acta., 3, 631 (1969).

  4. (4)

    H. G. Mayfield, Jr. and W. E. Bull,Inorg. Chim. Acta., 3∶4, 676 (1969).

  5. (5)

    C. Calvo, N. C. Jayadevan, C. J. L. Lock and R. Restiva,Can. J. Chem., 48, 219 (1970).

  6. (6)

    C. Calvo, N. C. Jayadevan and C. J. L. Lock,Can. J. Chem., 47, 4213 (1969).

  7. (7)

    G. Vicentini, M. Perrier and J. C. Prado,J. Inorg. Nucl. Chem., 31, 825 (1969).

  8. (8)

    M. Perrier and G. Vicentini,J. Inorg. Nucl., Chem., 33, 2497 (1971).

  9. (9)

    A. M. P. Felicissimo, G. Vicentini and L. B. Zinner,J. Inorg. Nucl. Chem., 39, 1835 (1977).

  10. (10)

    K. Umeda, Report 1977, IEA-DT-039, p. 50;Chem. Abstr. 91, 12924 (1979).

  11. (11)

    I. B. Liss and E. O. Schlemper,Inorg. Chem., 14, 3035 (1975).

  12. (12)

    W. A. Nugent and R. L. Harlow,J. Chem. Soc. Chem. Comm., 1105 (1979).

  13. (13)

    E. Wilke-Dörfurt and T. Gunzert,Z. Anorg. Allg. Chem., 215, 369 (1933).

  14. (14)

    G. W. Watt and R. J. Thompson,Inorg. Synth., 7, 187 (1963).

  15. (15)

    H. H. Willard and G. M. Smith,Ind. Eng. Chem. Anal. Edit., 11, 305 (1939).

  16. (16)

    B. N. Figgis and R. S. Nyholm,J. Chem. Soc., 381 (1959).

  17. (17)

    B. N. Figgis and J. Lewis,Progr. Inorg. Chem., 6, 138 (1964).

  18. (18)

    A. Earnshaw,Introduction to Magnetochemistry, Academic Press, New York, 1968, p. 5.

  19. (19)

    E. S. Freeman and B. Carroll,J. Phys. Chem., 62, 394 (1958).

  20. (20)

    N. Weinstock, H. Schulze and A. Müller,J. Chem. Phys., 59, 5063 (1973).

  21. (21)

    B. Jezowska-Trzebiatowska, J. Hanuza and M. Baluka,Spectrochim. Acta., 27A, 1753 (1972).

  22. (22)

    A. B. P. Lever,Coord. Chem. Rev., 3, 119 (1968).

  23. (23)

    D. W. Rowley and R. S. Drago,Inorg. Chem., 7, 795 (1968).

  24. (24)

    A. Schreiner and D. J. Hamm,Inorg. Chem., 12, 2037 (1973).

  25. (25)

    R. L. Chiang and R. S. Drago,Inorg. Chem., 10, 453 (1971).

  26. (26)

    J. C. Donini, B. R. Hollebone, G. London, A. B. P. Lever and J. C. Hempel,Inorg. Chem., 14, 455 (1975).

  27. (27)

    Ref. 17, p. 207.

  28. (28)

    A. Müller, I. Boschen and W. Sievert,Z. Naturforsch., 25b, 311 (1970).

  29. (29)

    A. Müller, P. Christophliemk and I. Tossidis,J. Mol. Str., 15, 289 (1973).

Download references

Author information

Correspondence to Mukul C. Chakravorti.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Chakravorti, M.C., Sarkar, M.B. & Bharadwaj, P.K. Rhenium part XV. Tetragonal complexes of nickel(II) containing coordinated perrhenate [ReO4] . Transition Met Chem 6, 211–214 (1981). https://doi.org/10.1007/BF00618225

Download citation

Keywords

  • Ammonia
  • Physical Chemistry
  • Nickel
  • Inorganic Chemistry
  • Pyridine