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Benzoxazolinones

VI. Reaction of benzoxazolinone and of benzoazolinethione with substituted α-halo carbonyl compounds

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Abstract

The alkylation of the potassium and triethylammonium salts of benzoxazolinones and benzoxazolinethiones with α-halo carbonyl compounds has been studied. The reaction takes place at the less electronegiative atoms of the ambident benzoxazolinone and benzoxazolinethione anions. On the nitration of 3-phenacylbenzoxazoline moiety of the molecule.

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Literature cited

  1. 1.

    Chin-Ming Chen and Ming-Tyan Chen, Phytochemistry,15, No. 12, 1997 (1976).

  2. 2.

    S. N. Ivanova et al., in: Reactions and Methods of Investigating Organic Compounds [in Russian], Khimiya, Moscow (1983), p. 72.

  3. 3.

    R. L. Wain, Proc. R. Soc. (London), Sect. B,191, 335 (1975).

  4. 4.

    N. N. Mel'nikov, New Pesticides [in Russian], Moscow (1970), p. 80.

  5. 5.

    R. Cremlyn, Presticides, Wiley, New York (1979), p. 126.

  6. 6.

    R. G. Aflyatunova, N. A. Aliev, Ch. Sh. Kadyrov, and M. R. Yagudaev, Khim. Prir. Soedin., 507 (1983).

  7. 7.

    N. S. Vol'fson, Preparative Organic Chemistry [in Russian], Khimiya, Leningrad, pp. 214, 282, 841.

  8. 8.

    H. Gross and I. Gloede, Z. Chem.,5, 178 (1965).

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Additional information

Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 411–415, May–June, 1987.

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Aflyatunova, R.G., Babakhanova, K.R. & Aliev, N.S. Benzoxazolinones. Chem Nat Compd 23, 340–344 (1987). https://doi.org/10.1007/BF00600836

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Keywords

  • Potassium
  • Organic Chemistry
  • Carbonyl
  • Nitration
  • Carbonyl Compound