Chemistry of Natural Compounds

, Volume 22, Issue 6, pp 645–651 | Cite as

Triterpenoids from species ofAbies hill. II. Abiesolidic acid — A new 3,4-secolanostanoid from the oleoresin ofAbies sibirica

  • V. A. Raldugin
  • Yu. V. Gatilov
  • T. V. Rybalova
  • Ya. V. Rashkes


The oleoresin of the Siberian fir has yielded a new 3,4-secolanostanoid for which the structure of (20R,23S,25R)-3,4-seco-9β-lanosta-4(28),7-dien-26,23-olid-3-oic acid has been established by x-ray structural analysis. The pathways of the mass-spectrometric fragmentation of this acid and its esters have been investigated.


Triol Exomethylene Me2o Saturated Aqueous Sodium Chloride Permanent Yellow 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    G. V. Pigulevskii and V. G. Kostenko, in: Questions on the Chemistry of Terpenes and Terpenoids [in Russian], Vilnius (1960), p. 147.Google Scholar
  2. 2.
    V. A. Raldugin, O. V. Sudakova, V. I. Bol'shakova, N. I. Yaroshenko, É. N. Shmidt, and V. A. Pentegova, Khim. Prir. Soedin., 516 (1986).Google Scholar
  3. 3.
    V. A. Raldugin, Yu. V. Gatilov, I. Yu. Bagryanskaya, and N. I. Yaroshenko, Khim. Prir. Soedin., 584 (1986).Google Scholar
  4. 4.
    H. Irie, S. Uyeo, and K. Kuriyama, Tetrahedron Lett., 3647 (1971).Google Scholar
  5. 5.
    A. Yogev, D. Amar, and Y. Mazur, J. Chem. Soc., Chem. Commun., 339 (1967).Google Scholar
  6. 6.
    D. Arigoni, D. H. R. Barton, R. Bernasconi, C. Djerassi, J. S. Mills, and R. E. Wolff, J. Chem. Soc., 1900 (1960).Google Scholar
  7. 7.
    R. T. Aplin and I. R. Cox, Organ. Mass Spectrom.,10, 981 (1975).CrossRefGoogle Scholar
  8. 8.
    Y. Arai, K. Masuda, and H. Ageta, Chem. Pharm. Bull.,30, 4219 (1982).CrossRefGoogle Scholar

Copyright information

© Plenum Publishing Corporation 1987

Authors and Affiliations

  • V. A. Raldugin
  • Yu. V. Gatilov
  • T. V. Rybalova
  • Ya. V. Rashkes

There are no affiliations available

Personalised recommendations