Advertisement

Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Photocatalytic formation of hydrogen in alcoholic solutions of titanium tetrachloride

  • 54 Accesses

  • 1 Citations

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    W. M. Latimer, The Oxidation States of the Elements and Their Potentials in Aqueous Solutions, Prentice-Hall, New Jersey (1952).

  2. 2.

    K. I. Zamaraev and V. N. Parmon, “Possible routes and perspectives for the creation of photocatalytic solar energy converters,” in: The Transformation of Solar Energy [in Russian], Chernogolovka (1981), pp. 43–82.

  3. 3.

    F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Interscience, New York (1968).

  4. 4.

    I. A. Potapov, M. V. Rozenkevich, and Yu. A. Sakharovskii, “On the formation of hydrogen during the photolysis of aqueous-ethanolic solutions of Ti(IV),” Koordinats. Khim.,7, No. 2, 229–231 (1981).

  5. 5.

    A. I. Kryukov and Z. A. Tkachenko, “Titanium chloride sensitized liquid phase photocatalytic oxidation of ethanol,” Dokl. Akad. Nauk SSSR,203, No. 2, 372–375 (1972).

  6. 6.

    A. I. Kryukov, S. Ya. Kuchmii, A. V. Korzhak, and Z. A. Tkachenko, “On the mechanism of the photochemical reduction of titanium(IV) in alcoholic solutions,” Dokl. Akad. Nauk SSSR,222, No. 5, 1134–1137 (1975).

  7. 7.

    A. I. Kryukov, “Phototransfer of an electron in complex compounds and the initiation of photochemical organic reactions,” Doctoral Dissertation, Kiev (1979).

  8. 8.

    A. I. Kryukov, V. P. Sherstyuk, and I. I. Dilung, Electron Phototransfer and Its Applied Aspects [in Russian], Naukova Dumka, Kiev (1982).

  9. 9.

    S. Ya. Kuchmii, A. V. Korzhak, and A. I. Kryukov, “Spectroscopic study of the state of Ti(III) ions in aqueous-alcoholic solutions,” Teor. Éksp. Khim.,19, No. 5, 590–594 (1983).

  10. 10.

    A. I. Kryukov, A. V. Korzhak, and S. Ya. Kuchmii, “Photolysis of titanium tetrachloride in ethanol under the action of light with λ=254 nm,” Teor. Éksp. Khim.,20, No. 1, 36–43 (1984).

  11. 11.

    D. M. Gruen and R. L. McBeth, “Absorption spectra of the d-state ions TiCl6 3−, TiCl4 , CrCl4 2−, FeCl4 2−, and CuCl4 2− in chloride melts,” Nature,194, No. 4827, 468 (1962).

  12. 12.

    Ya. G. Goroshchenko, Chemistry of Titanium [in Russian], Part 1, Naukova Dumka, Kiev (1970).

  13. 13.

    B. V. Koryakin, T. S. Dzhabiev, and A. E. Shilov, “Photocatalytic evolution of hydrogen from aqueous-alcoholic solutions of vanadium trichloride,” Dokl. Akad. Nauk SSSR,229, No. 1, 128–130 (1976).

  14. 14.

    N. M. Bazhin and V. M. Berdnikov, “Electron phototransfer reaction in the condensed phase,” in: Free Radical States in Chemistry [in Russian], Nauka, Novosibirsk (1972), pp. 129–153.

Download references

Author information

Additional information

Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 20, No. 2, pp. 169–177, March–April, 1984.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Kryukov, A.I., Korzhak, A.V. & Kuchmii, S.Y. Photocatalytic formation of hydrogen in alcoholic solutions of titanium tetrachloride. Theor Exp Chem 20, 161–168 (1984). https://doi.org/10.1007/BF00592802

Download citation

Keywords

  • Hydrogen
  • Titanium
  • Tetrachloride
  • Alcoholic Solution
  • Titanium Tetrachloride