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Topological nature of intrinsic structural defects in a trans-polyacetylene chain

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Abstract

Using a topological approach, we consider the nature of intrinsic structural defects in a real trans-polyacetylene chain. We show that remnant cis segments are internal diaclination loops having two components: a wedge loop of strength ±π/3 and a twist loop of strength π, while defects of the soliton type are a combination of a point dislocation and an external twist disclination loop of strength π.

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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 25, No. 1, pp. 71–74, January–February, 1989.

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Posudievskii, O.Y., Posudievskii, A.Y. & Korol', É.N. Topological nature of intrinsic structural defects in a trans-polyacetylene chain. Theor Exp Chem 25, 63–65 (1989). https://doi.org/10.1007/BF00580299

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Keywords

  • Soliton
  • Structural Defect
  • Topological Nature
  • Topological Approach
  • Soliton Type