Terpene amines. V. Synthesis and study of the structure of N-substituted tetrahydroionylamines
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The catalytic hydroamination of a mixture of α- and β-ionones by aliphatic nitriles and amines has been studied. A scheme of the occurrence of the reaction has been put forward. It has been established that the reaction forms in each case a mixture of secondary amines containing two pairs of diastereomers. The optimum conditions for the performance of the process have been determined.
KeywordsSecondary Amine Reductive Amination Propylamine Lithium Hydroxide Aliphatic Nitrile
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