Chemistry of Natural Compounds

, Volume 19, Issue 4, pp 422–425 | Cite as

Heterogeneous hydrogenation of 3,7,7-trimethylcyclohepta-1,3,5-triene

  • É. N. Manukov
  • V. A. Chuiko
Article
  • 36 Downloads

Abstract

It has been shown that the intermediate products of the hydrogenation of 3,7,7-trimethylcyclohepta-1,3,5-triene on platinum black are 2- and 3-carenes, in addition to olefins and dienes of the 1,1,4-trimethylcycloheptane series. The final hydrogenation product contains 96% of 1,1,4-trimethylcycloheptane and 4% of caranes.

Keywords

Diene Caranes Olefinic Proton TRITERPENE Glycoside Hederagenin 

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Literature cited

  1. 1.
    N. E. Frankel, J. Org. Chem.,37, 1549 (1972).CrossRefGoogle Scholar
  2. 2.
    A. Nakamura and S. Otsuka, Tetrahedron Lett., 4529 (1973).Google Scholar
  3. 3.
    E. Ciganec, J. Am. Chem. Soc.,93, 2207 (1971).CrossRefGoogle Scholar
  4. 4.
    R. B. Turner, B. J. Mallon, M. Tichy, W. v. E. Doering, W. R. Roth, and G. Schroeder, J. Am. Chem. Soc.,95, 8605 (1973).CrossRefGoogle Scholar
  5. 5.
    É. N. Manukov, V. A. Chuko, and P. V. Kuz'michkin, Khim. Prir. Soedin., 783 (1979).Google Scholar
  6. 6.
    R. V. Bates, W. N. Deines, D. A. McCombs, and D. E. Potter, J. Am. Chem. Soc.,91, 4608 (1966).CrossRefGoogle Scholar
  7. 7.
    W. Cocker, P. V. R. Shannon, and P. A. Staniland, J. Chem. Soc., (C), 41 (1966).Google Scholar
  8. 8.
    É. A. Karakhanov, A. G. Dedov, and A. S. Loktev, Khim. Geterotsikl. Soedin., 1332 (1981).Google Scholar
  9. 9.
    V. G. Dashevskii, V. A. Naumov, and N. M. Zaripov, Zh. Strukt. Khim.,13, 171 (1972).Google Scholar
  10. 10.
    B. G. Udarov, G. V. Deshchits, N. G. Zimina, and I. I. Bardyshev, Izv. Akad. Nauk BSSR, Ser. Khim. Nauk, 128 (1979).Google Scholar
  11. 11.
    G. Ohloff, K. H. Schulte-Elte, and W. Giersch, Helv. Chim. Acta,48, 1665 (1965).CrossRefGoogle Scholar
  12. 12.
    I. I. Bardyshev, G. V. Deshchits, and A. A. Vakhrameeva, Izv. Akad. Nauk BSSR, Ser. Khim. Nauk, 90 (1979).Google Scholar
  13. 13.
    D. Tishchenko and A. Khovanskaya, Zh. Obshch. Khim.,20, 1003 (1950).Google Scholar
  14. 14.
    V. A. Mironov and A. A. Akhrem, Izv. Akad. Nauk SSSR, Ser. Khim., 1851 (1972).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • É. N. Manukov
  • V. A. Chuiko

There are no affiliations available

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