Springer Nature is making SARS-CoV-2 and COVID-19 research free. View research | View latest news | Sign up for updates

Structure of aconifine

  • 65 Accesses

  • 5 Citations

Abstract

The structure of the new alkaloid aconifine, which has been isolated from the tubers and epigeal part ofAconitum karakolicum Rapcs. has been established on the basis of the results of chemical transformations and spectral characteristics. Some features of the selective acetylation of aconitine and aconine have been elucidated.

This is a preview of subscription content, log in to check access.

Literature cited

  1. 1.

    H. Chikamatsu, M. Tomita, and M. Kotake, J. Chem. Soc. Jpn.,82, 1708 (1961).

  2. 2.

    A. Kh. Yunusov, I. A. Israilov, and M. S. Yunusov, Khim. Prir. Soedin., 681 (1973).

  3. 3.

    M. N. Sultankhodzhaev, L. V. Beshitaishvili, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 826 (1979).

  4. 4.

    M. N. Sultankhodzhaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 127 (1973).

  5. 5.

    M. S. Yunusov, Ya. V. Rashkes, and S. Yu. Yunusov, Khim. Prir. Soedin., 626 (1971).

  6. 6.

    M. N. Sultankhodzhaev and M. S. Yunusov, Khim. Prir. Soedin., 481 (1975).

  7. 7.

    M. S. Yunusov, Ya. V. Rashkes, and S. Yu. Yunusov, Khim. Prir. Soedin., 85 (1972).

  8. 8.

    V. E. Nezhevenko, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 389 (1975).

  9. 9.

    M. S. Yunusov, V. E. Nezhevenko, and S. Yu. Yunusov, Khim. Prir. Soedin., 770 (1975).

  10. 10.

    Y. Tsuda and L. Marion, Can. J. Chem.,41, 1634 (1963).

  11. 11.

    M. S. Yunusov and S. Yu. Yunusov, Khim. Prir. Soedin., 90 (1970).

  12. 12.

    M. N. Sultankhodzhaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 199 (1973).

  13. 13.

    S. W. Pelletier, L. H. Keith, and P. C. Parthasarthy, J. Am. Chem. Soc.,89, 4146 (1967).

  14. 14.

    D. J. McCaldin and L. Marion, Can. J. Chem.,37, 1071 (1959).

  15. 15.

    T. Shima and T. Amija, Bull. Chem. Soc. Jpn.,31, 657 (1958).

  16. 16.

    K. Wiesner, M. Gots, D. L. Simmons, and L. R. Fowler, Collect. Czech. Chem. Commun.,28, No. 9, 2462 (1963).

  17. 17.

    O. Achmatowicz, Y. Tsudo, and L. Marion, Can. J. Chem.,43, 2336 (1965).

  18. 18.

    V. E. Nezhevenko, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 409 (1974).

  19. 19.

    A. S. Narzullaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 489 (1972).

  20. 20.

    A. S. Narzullaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 443 (1973).

  21. 21.

    S. W. Pellitier and Z. Djarmati, J. Am. Chem. Soc.,98, No. 9, 2626 (1976).

  22. 22.

    S. W. Pelletier, N. V. Mody, R. S. Sawhney, and J. Bhattacharyya, Heterocycles,7, No. 1, 327 (1977).

  23. 23.

    S. W. Pelletier, N. V. Mody, and R. S. Sawhney, Can. J. Chem.,57, No. 13, 1652 (1979).

  24. 24.

    M. N. Sultankhodzhaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prir. Soedin., 381 (1975).

  25. 25.

    B. Capon, Quart. Revs.,18, 45 (1964).

  26. 26.

    I. D. Sadenov, V. I. Minkin, and A. E. Lutskin, Usp. Khim.,39, No. 3, 380 (1970).

Download references

Additional information

Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 665–672, September–October, 1980.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Sultankhodzhaev, M.N., Beshitaishvili, L.V., Yunusov, M.S. et al. Structure of aconifine. Chem Nat Compd 16, 481–486 (1980). https://doi.org/10.1007/BF00571044

Download citation

Keywords

  • Alkaloid
  • Hydroxy Group
  • Acetic Anhydride
  • Acetyl Chloride
  • Epigeal Part