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13C NMR spectra of acetylated methyl glycosides of monosaccharides

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Summary

A comparative discussion of the signals in the13C NMR spectra of acetylated methyl α- and β-D-xylopyranosides, α- and β-D-glucopyranosides, α- and β-D-galactopyranosides, α- and β-L-arabinopyranosides, α- and β-L-fucopyranosides, and α- and β-L-rhamnopyranosides and of the corresponding free glycosides has shown a similarity of the effects of substitution at C5 with a longer-range nature of these effects in the case of the acetylated glycosides.

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Literature cited

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Additional information

Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center of the Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 6–8, January–February, 1979.

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Kalinovskii, A.I., Evtushenko, E.V. 13C NMR spectra of acetylated methyl glycosides of monosaccharides. Chem Nat Compd 15, 4–6 (1979). https://doi.org/10.1007/BF00570837

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Keywords

  • Methyl
  • Organic Chemistry
  • Glycoside
  • Monosaccharide
  • Comparative Discussion