Chemistry of Natural Compounds

, Volume 11, Issue 4, pp 498–502 | Cite as

The structure of karakolidine

  • M. N. Sultankhodzhaev
  • M. S. Yunusov
  • S. Yu. Yunusov
Article
  • 27 Downloads

Summary

As the result of a study of chemical transformations and spectral characteristics, for the new alkaloid karakolidine a lycoctonine skeleton with N-ethyl and C4-methyl groups, hydroxy groups at C1 (α), C8, C10 (α), and C13, and a methoxy group at C15 (β) has been established.

Some peculiarities of the fragmentation of derivatives of karakoline and karakolidine under the action of electron impact have been found.

Keywords

Hydroxy Group Sodium Carbonate Methoxy Group Acetyl Chloride Olefinic Proton 

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Literature cited

  1. 1.
    M. N. Sultankhodzhaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 127 (1973).Google Scholar
  2. 2.
    M. N. Sultankhodzhaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 199 (1973).Google Scholar
  3. 3.
    M. N. Sultankhodzhaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., No. 3, 381 (1975).Google Scholar
  4. 4.
    M. S. Yunusov and S. Yu. Yunusov, Khim. Prirodn. Soedin., 90 (1970).Google Scholar
  5. 5.
    K. Wiesner, F. Bickelhaupt, and D. Babin, Experentia,15, 93 (1959).CrossRefGoogle Scholar
  6. 6.
    S. W. Pelletier, L. H. Keith, and P. C. Parmasarafy, J. Amer. Chem. Soc.,89, 4146 (1967).CrossRefGoogle Scholar
  7. 7.
    O. Achmatowicz, Y. Tsuda, L. Marion, T. Okomoto, Natsume Mitsutaka, Chang Hong Hsi, and K. Kajima, Can. J. Chem.,4, 43 (1965).Google Scholar
  8. 8.
    M. S. Yunusov, Ya. V. Rashkes, V. A. Tel'nov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 515 (1969).Google Scholar
  9. 9.
    O. Achmatowicz, Y. Tsuda, and L. Marion, Can. J. Chem.,43, 2336 (1965).CrossRefGoogle Scholar
  10. 10.
    M. S. Yunusov, Ya. V. Rashkes, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 85 (1972).Google Scholar
  11. 11.
    A. S. Narzullaev, M. S. Yunusov, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 497 (1973).Google Scholar
  12. 12.
    M. S. Yunusov, Ya. V. Rashkes, and S. Yu. Yunusov, Khim. Prirodn. Soedin., 626 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • M. N. Sultankhodzhaev
  • M. S. Yunusov
  • S. Yu. Yunusov

There are no affiliations available

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