Chemistry of Natural Compounds

, Volume 7, Issue 4, pp 429–431 | Cite as

Steric effects in the iodomethylation of spatial isomers of matridine

  • A. I. Begisheva
  • Z. U. Petrochenko
  • Kh. A. Aslanov
  • A. S. Sadykov
Article
  • 21 Downloads

Summary

  1. 1.

    Only that nitrogen atom of a heterocyclic molecule can take part in the iodomethylation reaction for which a methyl group, after addition to it, undergoes no steric hindrance.

     
  2. 1.

    The rapid thermolysis of the methiodides of the isomers studied leads to partial demethylation without the decomposition of the molecule of the base itself.

     

Keywords

Nitrogen Atom Methyl Iodide Initial Base Thermolysis Product Methiodide 

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Literature cited

  1. 1.
    K. Tsuda and H. Mishima, J. Org. Chem.,23, 1179 (1958).CrossRefGoogle Scholar
  2. 2.
    A. I. Begisheva, Kh. A. Aslanov, Z. U. Petrochenko, and A. S. Sadykov, Khim. Prirodn. Soedin.,7, 55 (1971).Google Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1973

Authors and Affiliations

  • A. I. Begisheva
  • Z. U. Petrochenko
  • Kh. A. Aslanov
  • A. S. Sadykov

There are no affiliations available

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