Claisen rearrangement taking place in the mass spectrometer
Article
First Online:
Received:
- 17 Downloads
Conclusions
The Claisen rearrangement of bucharaine and of the aldehyde bucharainal takes place under the conditions of mass spectrometry. At low temperatures γ inversion predominates and at high temperatures the anomalous β rearrangement.
Keywords
Ring Form Ring Closure Chain Form Deuterium Atom Claisen RearrangementPreview
Unable to display preview. Download preview PDF.
Literature cited
- 1.Z. Sh. Faizutdinova, I. A. Bessonova, Ya. V. Rashkes, and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds], 239 (1970).Google Scholar
- 2.S. M. Sharafutdinova and S. Yu. Yunusov, KhPS [Chemistry of Natural Compounds], 198, 264 (1968).Google Scholar
- 3.J. G. Burr, J. M. Scarborough, and R. H. Shudde, J. Phys. Chem.,64, 1359 (1960).CrossRefGoogle Scholar
- 4.Organic Reactions [Russian translation], No. 2 (1950), p. 22.Google Scholar
- 5.R. A. Corral and O. O. Orazi, Tetrah.,21, 909 (1965).CrossRefGoogle Scholar
Copyright information
© Consultants Bureau, a division of Plenum Publishing Corporation 1973