Chemistry of Natural Compounds

, Volume 6, Issue 5, pp 593–597 | Cite as

Claisen rearrangement taking place in the mass spectrometer

  • Ya. V. Rashkes
  • Z. Sh. Faizutdinova
  • I. A. Bessonova
  • S. Yu. Yunusov
Article
  • 17 Downloads

Conclusions

The Claisen rearrangement of bucharaine and of the aldehyde bucharainal takes place under the conditions of mass spectrometry. At low temperatures γ inversion predominates and at high temperatures the anomalous β rearrangement.

Keywords

Ring Form Ring Closure Chain Form Deuterium Atom Claisen Rearrangement 

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Literature cited

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Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1973

Authors and Affiliations

  • Ya. V. Rashkes
  • Z. Sh. Faizutdinova
  • I. A. Bessonova
  • S. Yu. Yunusov

There are no affiliations available

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