Russian Physics Journal

, Volume 38, Issue 2, pp 138–142 | Cite as

Effects of a nonpoint ion lattice field on the radial wave functions of Tl+

  • M. U. Belyi
  • B. A. Okhrimenko
Semiconductor And Insulator Physics
Received:

Abstract

Radial d and s electron wave functions have been calculated for Tl+ in the 5d106s2 configuration in a crystalline field. One corrects for the effects of the nonpoint lattice ions on the wave functions by means of an approximation in which the lattice is considered as a set of charged spheres. The calculations are performed in the central-field approximation by the Hartree-Torrance method without allowance for the exchange interaction. The nonpoint correction leads to some consolidation of the wave functions by comparison with the point-ion approximation. The energy eigenvalues for the d and s electrons are altered. The calculations agree with increase in the binding energy between the central ion and the ligands in thallium halide complexes in the series Cl−→Br−→I−.

Keywords

Wave Function Binding Energy Halide Exchange Interaction Thallium 
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Copyright information

© Plenum Publishing Corporation 1995

Authors and Affiliations

  • M. U. Belyi
  • B. A. Okhrimenko

There are no affiliations available

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