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Polarographic reduction of 1-substituted 1,2,4-triazoles

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Abstract

The polarographic reduction of 1-substituted 1,2,4-triazoles in dimethylformamide (DMF) and acetonitrile was studied. 1-Methyl-, 1-ethyl-, and 1,2,4-triazoles are not reduced on a mercury electrode over the range of potentials accessible for polarography. 1-Phenyl-1,2,4-triazole and 1-vinyl-1,2,4-triazole are reduced in acetonitrile via a one-electron mechanism at high negative potentials. The reduction of 1-vinyl-1,2,4-triazole is accompanied by polymerization of the electrolysis products. A possible mechanism for the electrochemical reduction is discussed.

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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 408–410, March, 1980.

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Ermakova, T.G., Gritsa, A.I., Deriglazov, N.M. et al. Polarographic reduction of 1-substituted 1,2,4-triazoles. Chem Heterocycl Compd 16, 313–315 (1980). https://doi.org/10.1007/BF00553902

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Keywords

  • Polymerization
  • Mercury
  • Organic Chemistry
  • Acetonitrile
  • Dimethylformamide