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Journal of Materials Science

, Volume 27, Issue 6, pp 1435–1439 | Cite as

Infrared spectra and composition dependence investigations of the vitreous V2O5/P2O5 system

  • A. H. Khafagy
  • M. A. Ewaida
  • A. A. Higazy
  • M. M. S. Ghoneim
  • I. Z. Hager
  • R. El-Bahnasawy
Papers

Abstract

A series of glasses in the V2O5-P2O5 system was prepared and their compositions analysed. The glass densities and molar volumes were determined. The results obtained revealed three compositional regions. In addition, the infrared absorption spectra of these glasses were measured at room temperature in the frequency range 1600–200 cm−1. The compositional dependence of the bands present, attributed to a given band and mode of vibration, was investigated. However, the infrared data confirmed the results obtained from the density and molar volume measurements.

Keywords

Polymer Absorption Spectrum Infrared Spectrum Molar Volume Volume Measurement 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    H. Harper and P. W. McMillan, Phys. Chem. Glasses15 (1974) 148.Google Scholar
  2. 2.
    M. Munakata, Solid State Electron.1 (1960) 159.CrossRefGoogle Scholar
  3. 3.
    Bh. V. Janakirama Rao, J. Amer. Ceram. Soc.49 (1966) 605.CrossRefGoogle Scholar
  4. 4.
    F. R. Land Sbergeral and P. J. Bray, J. Chem. Phys.53 (1970) 2757.CrossRefGoogle Scholar
  5. 5.
    A. A. Higazy and B. Bridge, Phys. Chem. Glasses26 (1985) 82.Google Scholar
  6. 6.
    A. A. Higazy, M. A. Ewaida, A. Hussein and R. M. El-Bahnasawy, Ind. J. Phys.63A(2) (1989) 124.Google Scholar
  7. 7.
    I. Simmon, in “Modern Aspects of the Vitreous State” edited by J. D. Mackenzie (Butterworths, London, 1960) pp. 120–151.Google Scholar
  8. 8.
    J. Reitzl, J. Chem. Phys.23 (1955) 2407.CrossRefGoogle Scholar
  9. 9.
    I. Simmon and H. O. McHahon, J. Chem. Phys.21 (1953) 21.Google Scholar
  10. 10.
    G. J. Su, N. U. Borrell and A. R. Miller, Phys. Chem. Glasses3(S) (1962) 167.Google Scholar
  11. 11.
    N. F. Borrelli and G. J. Su, ibid.4 (1963) 206.Google Scholar
  12. 12.
    C. K. Shih and G. J. Su, in “Proceedings of the seventh International Congress on Glass”, Brussels, Paper 48 (1965) p. 133.Google Scholar
  13. 13.
    A. A. Higazy and B. Bridge, J. Mater. Sci.20 (1985) 2345.CrossRefGoogle Scholar
  14. 14.
    N. F. Borrelli and G. J. Su, Mater. Res. Bull.3 (1968) 181.CrossRefGoogle Scholar
  15. 15.
    R. M. Almeida and J. D. Makenzie, J. Non-Cryst. Solids40 (1980) 535.CrossRefGoogle Scholar
  16. 16.
    VOGEL's “Textbook of Quantitative Inorganic Analysis”, 4th Edn (ELBS Longman, 1985) pp. 390, 498.Google Scholar
  17. 17.
    L. W. Andrews, J. Amer. Chem. Soc.25 (1903) 756.CrossRefGoogle Scholar
  18. 18.
    G. S. Jamieson, “Volumetric Iodate Methods” (Reinhold, New York, 1926).Google Scholar
  19. 19.
    Bh. V. Janakirama-Rao, J. Amer. Ceram. Soc.48 (1965) 311.CrossRefGoogle Scholar
  20. 20.
    C. Calvo and B. D. Jordan, Phys. Chem. Glasses17 (1976) 220.Google Scholar
  21. 21.
    C. F. Drake, T. A. Stephan and B. Yates, J. Non-Cryst. Solids28 (1978) 61.CrossRefGoogle Scholar
  22. 22.
    M. N. Khan, R. Harani, M. M. Ahmed and C. A. Hogarth, J. Mater. Sci.20 (1985) 2207.CrossRefGoogle Scholar
  23. 23.
    G. W. Anderson and W. D. Compton, J. Chem. Phys.52 (1970) 6166.CrossRefGoogle Scholar
  24. 24.
    M. Sayer, A. Mansingh, J. M. Reyes and G. F. Lynch, in “Proceedings of the 2nd International Conference in Low Mobility Materials” Eilat, Israel (Taylor and Francis, 1971) p. 115.Google Scholar
  25. 25.
    F. Dachille and R. Roy, ibid.42 (1965) 78.Google Scholar
  26. 26.
    N. A. Ghoneim, J. Non-Cryst. Solids56 (1983) 367.CrossRefGoogle Scholar

Copyright information

© Chapman & Hall 1992

Authors and Affiliations

  • A. H. Khafagy
    • 1
  • M. A. Ewaida
    • 1
  • A. A. Higazy
    • 1
  • M. M. S. Ghoneim
    • 1
  • I. Z. Hager
    • 1
  • R. El-Bahnasawy
    • 1
    • 2
  1. 1.Physics Department, Faculty of ScienceMenoufia UniversityShebin El-KoomEgypt
  2. 2.Chemistry Department, Faculty of ScienceMenoufia UniversityShebin El-KoomEgypt

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