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Journal of Materials Science

, Volume 23, Issue 10, pp 3572–3577 | Cite as

The carbothermal reduction process of a montmorillonite-polyacrylonitrile intercalation compound

  • Yoshiyuki Sugahara
  • Kazuyuki Kuroda
  • Chuzo Kato
Article

Abstract

To develop a carbothermal reduction process for the conversion of oxides to nitrides, a montmorillonite-polyacrylonitrile (PAN) intercalation compound was applied as a precursor. Montmorillonite-carbon mixtures were heated as well as the intercalation compound in N2 at 1100 to 1500° C for comparison. From the intercalation compound, β-sialon, AIN and SiC were mainly formed. Oxides were reduced without their crystallization. On the other hand, in the reactions of the mixtures, some oxides and other kinds of nitride were obtained as principal products in addition to these phases. Furthermore, the intercalation compound was more favourable than the mixtures having a larger amount of carbon in terms of the reduction of oxides and the formation of nitrides. These observations suggest that the layered structure of the intercalation compound led to an effective and specific carbothermal reduction process.

Keywords

Oxide Polymer Crystallization Nitrides Layered Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Chapman and Hall Ltd 1988

Authors and Affiliations

  • Yoshiyuki Sugahara
    • 1
  • Kazuyuki Kuroda
    • 1
  • Chuzo Kato
    • 1
  1. 1.Department of Applied Chemistry, School of Science and EngineeringWaseda UniversityTokyoJapan

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