Theoretical and Experimental Chemistry

, Volume 20, Issue 3, pp 298–303 | Cite as

Complex compounds of iron and ruthenium with 2,2′-bipyridine in oscillating chemical reactions

  • L. P. Tikhonova
  • K. B. Yatsimirskii
  • V. Ya. Zayats
Article

Keywords

Iron Ruthenium Bipyridine Complex Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. M. Zhabotinskii, Concentrational Selfoscillations [in Russian], Nauka, Moscow (1974).Google Scholar
  2. 2.
    A. S. Kovalenko, L. P. Tikhonova, O. M. Roizman, and E. V. Protopopov, “Characteristics of concentration regions of the existence of oscillations in Belousov-Zhabotinskii reactions”, Teor. Éksp. Khim., 16, No. 1, 46–52 (1980).Google Scholar
  3. 3.
    M. L. Smoes, “Period of homogenous oscillations in the ferroin-catalyzed Zhabotinskii system,” J. Chem. Phys., 71, No. 11, 4669–4671 (1979).Google Scholar
  4. 4.
    J. N. Demas and D. Diemente, “An oscillating chemical reaction with a luminescent indicator,” J. Chem. Educ., 50, No. 5, 357–358 (1973).Google Scholar
  5. 5.
    E. Körös, L. Ladayi, V. Friedrich, et al., “The Ru(dipy)3 2+-bromate-malonic acid system,” React. Kinet. and Catal. Lett., 1, No. 4, 455–460 (1974).Google Scholar
  6. 6.
    L. P. Tikhonova and V. Ya. Zayats, “Study of an oscillating chemical reaction with the participation of complexes of ruthenium(II) and ruthenium(III) with α,α′-bipyridine,” Teor. Éksp. Khim., 16, No. 4, 546–551 (1980).Google Scholar
  7. 7.
    V. A. Vavilin, G. V. Gulak, A. S. Zhabotinskii, and A. N. Zaikin, “Complex iron ions, catalysts of self-oscillating reaction of oxidation of malonic acid and its analogs by bromate,” Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2618–2619 (1969).Google Scholar
  8. 8.
    L. Kuhner and K. W. Pehl, “Oscillations in the Belousov-Zhabotinskii system (BZR) catalyzed by bis-pyridine-silver complexes,” Chem. Phys. Lett., 84, No. 1, 155–158 (1981).Google Scholar
  9. 9.
    L. Kuhnert and K. Pehl, “Bipyridine complexes of osmium and chromium catalyzing the oscillating reaction between bromate and malonic acid,” Chem. Phys. Lett. 84, No. 1, 159–162 (1981).Google Scholar
  10. 10.
    R. D. Gillard, “Equilibria in complexes of N-heterocyclic molecules. 3. An explanation for classical anomalies among complexes of 1,10-phenanthtrolines and 2,2′-bipyridyls,” Coord. Chem. Rev., 16, No. 112, 67–94 (1975).Google Scholar
  11. 11.
    I. M. Kolthoff, R. Belcher, V. A. Stenger, and G. Matsuyama, Volumetric Analysis, Vols. 1–3, Wiley, New York (1942–1957).Google Scholar
  12. 12.
    F. N. Burstall, “Optical activity dependent on coordinated bivalent ruthenium,” J. Chem. Soc., 139, No. 1, 173–176 (1936).Google Scholar
  13. 13.
    Q. G. Mulazzani, S. Emmi, and P. C. Fuochi, “On the nature of Ru(bipy)3 2+ in aqueous solution,” J. Am. Chem. Soc., 100, No. 3, 981–983 (1978).Google Scholar
  14. 14.
    M. S. Henry and M. Z. Hoffman, “Fluorescence from 2,2′-bipyridine. Evidence for covalent hydrate formation,” J. Am. Chem. Soc., 99, No. 15, 5201–5203 (1977).Google Scholar
  15. 15.
    P. Herbine and R. J. Field, “Simulation on the basis of a plausible skeleton mechanism of the chemical oscillation during the uncatalyzed reactions of aromatic compounds with bromate,” J. Phys. Chem., 84, No. 11, 1330–1332 (1980).Google Scholar
  16. 16.
    M. T. Beck, G. Basza, and K. Hauck, “Periodic reactions between bromate and ferrosin,” In: Kinetics of Physical-chemical oscillations: Procceedings of International Conference (Aachen), Vol. 1 (1979), pp. 123–131.Google Scholar
  17. 17.
    A. S. Kovalenko and L. P. Tikhonova, “Use of inert electrodes for recording concentrational oscillations in Belousov-Zhabotinskii reactions,” Teor. Éksp. Khim., 16, No. 3, 409–415 (1980).Google Scholar

Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • L. P. Tikhonova
    • 1
  • K. B. Yatsimirskii
    • 1
  • V. Ya. Zayats
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryAcademy of Sciences of the Ukrainian SSRKiev

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