Theoretical and Experimental Chemistry

, Volume 14, Issue 6, pp 651–653 | Cite as

On the effect of the 3d-orbitals of silicon on its acceptor properties in tetrahalides

  • S. L. Mironov
  • Yu. I. Gorlov
  • A. A. Chuiko
Brief Communications


Silicon Acceptor Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    L. Pauling, The Nature of the Chemical Bond [Russian translation], Goskhimizdat, Moscow (1947), p. 457.Google Scholar
  2. 2.
    A. N. Egorochkin, N. S. Vyazankin, and S. Ya. Khorshev, “Effect of dπ–pπ conjugation in Group 4B organic compounds,” Usp. Khim., 41, No. 5, 828–851 (1972).Google Scholar
  3. 3.
    A. A. Énnan and B. M. Kats, “Silicon tetrafluoride adducts,” Usp. Khim., 43, No. 7, 1186–1206 (1974).Google Scholar
  4. 4.
    D. P. Santry and G. A. Segal, “Approximate SC MO theory. IX. Calculation on molecules including the elements sodium through chlorine,” J. Chem. Phys., 47, No. 1, 156–174 (1967).Google Scholar
  5. 5.
    K. Wiberg, “Application of the CNDO method to the cyclopropylcarbynyl and cyclobutyl cation rearrangement and to cyclobutane,” Tetrahedron, 24, No. 3, 1084–1096 (1968).Google Scholar
  6. 6.
    D. R. Armstrong, P. L. Perkins, and J. J. P. Stewart, “Bond indices and valence,” J. Chem. Soc. Dalton Trans., No. 8, 838–840 (1973).Google Scholar
  7. 7.
    H. Fischer and H. Kollmar, “Energy partitioning with the CNDO method,” Theor. Chim. Acta, 16, No. 3, 163–173 (1970).Google Scholar
  8. 8.
    S. Ehrenson and S. Seltser, “On the CNDO bond indices and relation to molecular energies,” Theor. Chim. Acta, 20, No. 1, 17–30 (1971).Google Scholar
  9. 9.
    I. W. McIver and A. Komornicki, “Rapid geometry optimization for semiempirical MO method,” Chem. Phys. Lett., 10, No. 3, 303–307 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • S. L. Mironov
    • 1
  • Yu. I. Gorlov
    • 1
  • A. A. Chuiko
    • 1
  1. 1.L. V. Pisarzhevskii Institute of Physical ChemistryAcademy of Sciences of the Ukr. SSRKiev

Personalised recommendations