Fresenius' Zeitschrift für analytische Chemie

, Volume 330, Issue 3, pp 231–234 | Cite as

Supercritical fluid chromatography with redox chemiluminescence detection

  • William T. Foreman
  • Robert E. Sievers
  • Bernd W. Wenclawiak
Lectures and Posters

Summary

The new selective and sensitive redox chemiluminescence detector (RCD), originally developed for gas chromatography, has been successfully interfaced with a capillary column supercritical fluid chromatograph. Interfacing the SFC-RCD was accomplished simply through utilization of the redox reaction chamber presently used for both capillary and packed column GC. The feasibility of this new separation-detection scheme was demonstrated with SFC chromatograms of antioxidant isomers and some compounds of biological relevance. Mobile phase compatibility and signal quenching are also discussed.

Chromatographie mit überkritischen fluiden phasen unter Verwendung der Redox-Chemiluminescenz-Detektion

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References

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Copyright information

© Springer-Verlag 1988

Authors and Affiliations

  • William T. Foreman
    • 1
  • Robert E. Sievers
    • 1
  • Bernd W. Wenclawiak
    • 1
  1. 1.Cooperative Institute for Research in Environmental Sciences, and Department of Chemistry and BiochemistryUniversity of ColoradoBoulderUSA

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