Chemistry of Heterocyclic Compounds

, Volume 20, Issue 5, pp 515–518 | Cite as

Synthesis of 5-n-alkyl-2-(trans-4-n-alkylcyclohexyl)pyridines

  • A. I. Pavlyuchenko
  • G. V. Purvanetskas
  • V. K. Daukshas
  • N. I. Smirnova
  • N. I. Korotkova
  • E. I. Kovshev
Article
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Abstract

The cyclization of trans-1-acrylyl-4-n-alkylcyclohexanes with trans-1-N-piperidino-1-alkenes was used to synthesize 3-n-alkyl-6-(trans-4-n-alkyl-cyclohexyl)-3,4-dihydro-2-N-piperidino-2H-pyrans, which were converted under the influence of hydroxylamine to 5-n-alkyl-2-(trans-4-n-alkylcyclohexyl)-pyridines. Problems in the stereochemistry of the cyclohexane derivatives in the investigated scheme of synthesis were examined.

Keywords

Organic Chemistry Pyridine Cyclohexane Hydroxylamine Cyclohexane Derivative 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1984

Authors and Affiliations

  • A. I. Pavlyuchenko
    • 1
  • G. V. Purvanetskas
    • 1
  • V. K. Daukshas
    • 1
  • N. I. Smirnova
    • 1
  • N. I. Korotkova
    • 1
  • E. I. Kovshev
    • 1
  1. 1.Scientific-Research Institute of Organic Intermediates and DyesMoscow

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