Chemistry of Heterocyclic Compounds

, Volume 19, Issue 3, pp 332–336 | Cite as

Synthesis of bis(o-hydroxyphenyl)-1,3,5-triazines, 1,2,4-triazoles, and oxadiazole by recyclization of the o-hydroxyphenyl-4-oxo-1,3-benzoxazinium cation

  • Yu. I. Ryabukhin
  • L. N. Faleeva
  • V. G. Korobkova
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Abstract

The acidic cyclization of disalicylamide gave 2-(o-hydroxyphenyl)- and 2-(o-acetoxyphenyl)-4-oxo-1,3-benzoxazinium perchlorates, by reaction of which with hydroxylamine, hydrazines, benzamidine, guanidines, and S-methylisothiourea bis(o-hydroxyphenyl)-1,2,4-oxadiazole, triazoles, and sym-triazines were synthesized. Mono- and bis (o-acetoxyphenyl) triazoles were obtained.

Keywords

Organic Chemistry Hydrazine Perchlorate Triazole Guanidine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1983

Authors and Affiliations

  • Yu. I. Ryabukhin
    • 1
    • 2
  • L. N. Faleeva
    • 1
    • 2
  • V. G. Korobkova
    • 1
    • 2
  1. 1.Rostov-on-Don Institute of Agricultural Machine BuildingRostov-on-Don
  2. 2.Scientific-Research Institute of Physical and Organic Chemistry at Rostov State UniversityRostov-on-Don

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