Quaternary 1-aminobenzimidazolium salts in reactions with β-dicarbonyl compounds. Formation of pyridazino[1,6-a]benzimidazolium cations and 1-arylpyrazoles
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Abstract
Pyridazino[1,6-a]benzimidazolium cations and 1-(o-methylaminoaryl)-4-acetylpyrazoles are formed simultaneously in approximately equal amounts in the reaction of excess acetylacetone with quaternary 1-aminobenzimidazolium salts in aqueous potassium carbonate solution. Mesoionic pyridazinobenzimidazoles and the corresponding 4-ethoxycarbonylpyrazoles were obtained with acetoacetic ester under similar conditions.
Keywords
Ester Potassium Organic Chemistry Similar Condition Benzimidazolium
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© Plenum Publishing Corporation 1983