International Journal of Thermophysics

, Volume 13, Issue 2, pp 251–267 | Cite as

Viscosities of nonelectrolyte liquid mixtures. I. binary mixtures containing p-dioxane

  • S. L. Oswal
  • R. P. Phalak
Article
Received:

Abstract

Viscosity measurements are reported for p-dioxans with cyclohexane, n-hexane, benzene, toluene, carbon tetrachloride, tetrachloroethane, chloroform, pentachloroethane, and ethyl acetate at 303.15 K. Excess Gibbs energies of activation δG*E of viscous flow have been calculated with Eyring's theory of absolute reaction rates. The deviations of the viscosities from a linear dependence on the mole fraction and values of δG*E for binary mixtures have been explained in terms of molecular interactions between unlike pairs. The Prigogine-Flory-Patterson theory has been used to estimate the excess viscosity, δ ln η, and corresponding enthalpy ln ηH, entropy ln ηS, and free volume ln ηv terms for binary mixtures of p-dioxane with cyclohexane, n-hexane, benzene, toluene, carbon tetrachloride, and chloroform. Estimates of excess viscosities from this theory for p-dioxane with benzene, toluene, and carbon tetrachloride are good, while for the other three mixtures they are poor. The local-composition thermodynamic model of Wei and Rowley estimates the excess viscosity quite well even for p-dioxane mixtures with cyclohexane and n-hexane.

Key words

activation energy aromatic hydrocarbons chloroalkanes p-dioxane molecular interactions viscosity 
This is a preview of subscription content, log in to check access.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    A. W. Andrews and K. W. Macrom, J. Chem. Thermodyn. 3:513, 519 (1971).Google Scholar
  2. 2.
    D. D. Deshpande and S. L. Oswal, J. Chem. Soc. Faraday J. 68:1059 (1972).Google Scholar
  3. 3.
    D. D. Deshpande and S. L. Oswal, J. Chem. Thermodyn. 7:155 (1975).Google Scholar
  4. 4.
    S. L. Oswal and D. D. Deshpande, Int. Data Ser. Sel. Data Ser. A 1:7–36 (1988).Google Scholar
  5. 5.
    P. P. Singh, R. C. Phutela, and P. S. Arora, J. Chem. Soc. Faraday I 71:1528 (1975).Google Scholar
  6. 6.
    A. Inglese, E. Wilheim, J. P. E. Grolier, and H. V. Kehiaian, J. Chem. Thermodyn. 12:217, 1047 (1980).Google Scholar
  7. 7.
    C. J. Pederson and H. K. Frensdorff, Angew. Chem. 84:16 (1972).Google Scholar
  8. 8.
    D. J. Cram and J. M. Cram, Science 183:803 (1974).Google Scholar
  9. 9.
    R. J. Fort and W. R. Moore, Trans. Faraday Soc. 62:1112 (1966).Google Scholar
  10. 10.
    R. K. Nigam and B. S. Mahl, Ind. J. Chem. 9:1255 (1971).Google Scholar
  11. 11.
    S. L. Oswal, Can. J. Chem. 66:111 (1988).Google Scholar
  12. 12.
    S. L. Oswal and A. T. Patel, Int. J. Thermophys. 12:821 (1991).Google Scholar
  13. 13.
    I. Prigogine, Molecular Theory of Solution (North Holland, Amsterdam, 1957).Google Scholar
  14. 14.
    P. J. Flory, J. Am. Chem. Soc. 87:1833 (1965).Google Scholar
  15. 15.
    D. Patterson and G. Delmas, Disc. Faraday Soc. 49:98 (1970).Google Scholar
  16. 16.
    T. C. Wei and L. Rowley, J. Chem. Eng. Data 29:332 (1983).Google Scholar
  17. 17.
    I. C. Wei and R. L. Rowley, Chem. Eng. Sci. 40:401 (1985).Google Scholar
  18. 18.
    L. Ubbelohde, Ind. Eng. Chem. 9:85 (1937).Google Scholar
  19. 19.
    F. A. GonÇalves, J. Kestin, and J. V. Sengers, Int. J. Thermophys. (in press).Google Scholar
  20. 20.
    J. A., Riddick, W. B. Bunger, and T. K. Sakano, Organic Solvents Physical Properties and Methods of Purification, 4th ed. (Wiley Interscience, New York, 1986).Google Scholar
  21. 21.
    S. L. Oswal and I. N. Patel, Ind. J. Chem. A29:870 (1990).Google Scholar
  22. 22.
    R. H. Stokes, J. Chem. Thermodyn. 5:379 (1973).Google Scholar
  23. 23.
    K. Tamura, K. Ohomuro, and S. Murakami, J. Chem. Thermodyn. 15:859 (1983).Google Scholar
  24. 24.
    M. Aoi and M. Arakawa, Bull. Chem. Soc. Jap. 54:289 (1981).Google Scholar
  25. 25.
    M. D. Guillen and C. Gutierrey Losa, J. Chem. Thermodyn. 10:567 (1978).Google Scholar
  26. 26.
    S. Arrhenius, Z. Phys. Chem. 1:285 (1887).Google Scholar
  27. 27.
    S. Glasstone, K. J. Laidler, and H. Eyring, The Theory of Rate Processes (McGraw-Hill, New York, 1941).Google Scholar
  28. 28.
    P. K. Katti and M. M. Chaudhri, J. Chem. Eng. Data 9(3):442 (1952).Google Scholar
  29. 29.
    S. C. Sharma, M. L. Kakhanpal, and M. L. Rumpaul, Ind. J. Chem. 21A:67 (1982).Google Scholar
  30. 30.
    R. P. Phalak, M.Phil, dissertation (South Gujarat University, Surat, 1990).Google Scholar
  31. 31.
    M. L. McGlashan and R. P. Rastogi, Trans. Faraday Soc. 57:496 (1958).Google Scholar
  32. 32.
    I. R. McKinnon and A. G. Williamson, Aust. J. Chem. 17:1374 (1964).Google Scholar
  33. 33.
    L. A. Beath and A. G. Williamson, J. Chem. Thermodyn. 1:51 (1969).Google Scholar
  34. 34.
    N. Dasco, D. V. Fenby, and L. G. Helper, Can. J. Chem. 52:2139 (1974).Google Scholar
  35. 35.
    B. Ruitz, F. M. Royo, and S. Otin, J. Chem. Thermodyn. 20:239 (1988).Google Scholar
  36. 36.
    M. Kennard and P. A. McCusker, J. Am. Chem. Soc. 70:3375 (1948).Google Scholar
  37. 37.
    J. B. Ott, J. R. Goates, and N. F. Maugelson, J. Chem. Eng. Data 9:203 (1964).Google Scholar
  38. 38.
    S. L. Oswal and P. P. Palsanawala, Acoust. Lett. 13(4):66 (1989).Google Scholar
  39. 39.
    Cl. Jambon and G. Delmas, Can. J. Chem. 55:1360 (1977).Google Scholar
  40. 40.
    G. Delmas, P. Purves, and P. de Saint-Romain, J. Phys. Chem. 79:1970 (1975).Google Scholar
  41. 41.
    H. Phuong-Nguyen and G. Delmas, Can. J. Chem. 64:681 (1986).Google Scholar
  42. 42.
    V. A. Bloomfield and R. K. Dewan, J. Phys. Chem. 75:3113 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • S. L. Oswal
    • 1
  • R. P. Phalak
    • 1
  1. 1.Department of ChemistrySouth Gujarat UniversitySuratIndia

Personalised recommendations