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Chemistry of Heterocyclic Compounds

, Volume 11, Issue 4, pp 486–491 | Cite as

Heterocyclic analogs of pleiadiene. XVI. Nitration of perimidine and its 1- and 2-methyl derivatives

  • A. F. Pozharskii
  • V. N. Koroleva
Article

Abstract

Perimidine and 2-methylperimidine are nitrated by 1 mole of nitric acid in acetic acid to give a mixture of 4(9)- and 6(7)-mononitro derivatives. Renitration gives a mixture of 6,9- and 6,7-dinitroperimidines. Depending on the conditions, 6,7,9-trinitroperimidines and 4,6,7,9-tetranitroperimidines are formed when a large excess of nitric acid is present. 1-Methylperimidine is nitrated by 1 mole of nitric acid to give a mixture of 4-, 6-, and 7-mononitro derivatives.

Keywords

Acetic Nitrate Acetic Acid Organic Chemistry Nitric Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • A. F. Pozharskii
    • 1
  • V. N. Koroleva
    • 1
  1. 1.Rostov State UniversityRostov-on-Don

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