Chemistry of Heterocyclic Compounds

, Volume 12, Issue 7, pp 745–748 | Cite as

Synthesis of 2-thiabicyclo[3.2.0]hept-3-enes by reaction of acetylene with sodium sulfide

  • B. A. Trofimov
  • G. A. Kalabin
  • V. V. Kryuchkov
  • V. V. Keiko
  • S. V. Amosova
  • V. M. Bzhezovskii
  • V. K. Voronov
  • D. F. Kushnarev
  • V. Yu. Vitkovskii
  • L. I. Lavlinskaya
  • V. A. Pestunovich
Article
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Abstract

The previously unknown2-thiabicyclo[2.3.0]hept-3-ene and exo- and endo-6-methyl-2-thiabicyclo[3.2.0]hept-3-enes were synthesized in one step from acetylene and sodium sulfide in aqueous dimethyl disulfoxide.

Keywords

Sodium Sulfide Organic Chemistry Dimethyl Acetylene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • B. A. Trofimov
    • 1
  • G. A. Kalabin
    • 1
  • V. V. Kryuchkov
    • 1
  • V. V. Keiko
    • 1
  • S. V. Amosova
    • 1
  • V. M. Bzhezovskii
    • 1
  • V. K. Voronov
    • 1
  • D. F. Kushnarev
    • 1
  • V. Yu. Vitkovskii
    • 1
  • L. I. Lavlinskaya
    • 1
  • V. A. Pestunovich
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Academy of Sciences of the USSRUSSR

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