Synthesis and transformations of 2-(2-furyl)-and 2-[β;-(2-furyl)vinyl]naphth[1,2-d]imidazoles
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Abstract
The corresponding 2-(2-furyl)naphth[1,2-d]imidazoles were obtained by heating Schiff bases, prepared from 1,2-naphthalenediamine and furfural and 5-bromo- and 5-nitrofurfurals, in nitrobenzene. 2-[β-(2-Furyl)vinyl]naphth[1,2-d]imidazoles were synthesized by condensation of 2-methylnaphth[1,2-d]imidazole with furfural and 5-bromo- and 5-nitrofurfural. The methylation, nitration, and acetylation of the compounds obtained were studied, and the replacement of the bromine atom in the furan ring by a nitro group was also investigated.
Keywords
Methylation Organic Chemistry Vinyl Imidazole Schiff Base
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© Plenum Publishing Corporation 1974