Chemistry of Heterocyclic Compounds

, Volume 12, Issue 5, pp 520–523 | Cite as

Conformational analysis of the stereoisomers of 3-methyl-2-oxo-2-thiabicyclo[4.4.0]decane

  • E. N. Karaulova
  • L. M. Petrova
  • G. D. Gal'pern
  • S. G. Vul'fson
Article
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Abstract

The conditions for the separation of the stereoisomeric sulfones and sulfoxides of 3-methyl-2-thiabicyclo[4.4.0]decane were found by means of capillary gas-liquid chromatography, and the relative thermodynamic stabilities of the latter were determined. The configuration of the stereoisomeric sulfoxides was established on the basis of oxidation data, the characteristics of the physicochemical properties, and the Kerr effect.

Keywords

Oxidation Chromatography Sulfone Organic Chemistry Physicochemical Property 
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Copyright information

© Plenum Publishing Corporation 1977

Authors and Affiliations

  • E. N. Karaulova
    • 1
    • 2
  • L. M. Petrova
    • 1
    • 2
  • G. D. Gal'pern
    • 1
    • 2
  • S. G. Vul'fson
    • 1
    • 2
  1. 1.A. V. Topchiev Institute of Petrochemical SynthesisAcademy of Sciences of the USSRMoscow
  2. 2.Arbuzov Institute of Organic and Physical ChemistryKazan Branch of the Academy of Sciences of the USSRUSSR

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