Chemistry of Heterocyclic Compounds

, Volume 1, Issue 5, pp 450–454 | Cite as

Researches in the thiophene series

VIII. Gas-liquid chromatography of isomeric thienothiophenes
  • V. I. Yakerson
  • L. I. Lafer
  • V. P. Litvinov
Article

Abstract

Chromatographic behaviors of seven alkyl-substituted thienothiophenes and two acetylmercaptothiophenes are investigated. They are separated on a stationary phase of polyethyleneglycoladipate supported on diatomaceous brick or lining tile. A mixture of 3-methyl-5-ethylthieno [2, 3-b] thiophene and 3-methyl-5-ethylthieno [3, 2-b]-thiophene is analyzed quantitatively. The gas-liquid chromatographic method developed is used to elucidate the peculiarities of cyclization of acetonylmercaptothiophenes and isomeric thienothiophenes.

Keywords

Organic Chemistry Stationary Phase Thiophene Chromatographic Method Chromatographic Behavior 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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References

  1. 1.
    Ya. L. Gol'dfarb and V. P. Litvinov, Izv. AN SSSR, OKhN, 345, 1963.Google Scholar
  2. 2.
    Ya. L. Gol'dfarb and V. P. Litvinov, Izv. AN SSSR, OKhN, 352, 1963.Google Scholar
  3. 3.
    Ya. L. Gol'dfarb and V. P. Litvinov, Author's Certificate No. 157230, 25 July 1962, Byull izobret., no. 20, 14, 1963.Google Scholar
  4. 4.
    Ya. L. Gol'dfarb and V. P. Litvinov, Izv. AN SSSR, OKhN, 1621, 1963.Google Scholar
  5. 5.
    Ya. L. Gol'dfarb, V. P. Litvinov, V. A. Petukhov, and I. P. Yakovlev, Izv. AN SSSR, OKhN, 1627, 1963.Google Scholar
  6. 6.
    V. P. Litvinov and Ya. L. Gol'dfarb, Izv. AN SSSR, ser. khim., 2183, 1963Google Scholar
  7. 7.
    S. F. Birch, T. V. Cullum, R. A. Dean, and D. J. Redford, Tetrahedron, 7, 311, 1959.Google Scholar
  8. 8.
    H. E. Limpkin and B. H. Johnson, Anal. Chem., 26, 1719, 1954.Google Scholar
  9. 9.
    C. H. Amberg, J. Inst. Petrol., 45, 1, 1959.Google Scholar
  10. 10.
    F. Challenger and G. P. Harrison, J. Inst. Petrol., 21, 135, 1935.Google Scholar
  11. 11.
    H. D. Hartough, in: Adv. Petroleum Chemistry and Refining, New York-London, 3, 419, 1960.Google Scholar
  12. 12.
    D. H. Desty and B. H. F. Whyman, Anal. Chem., 29, 320, 1957.Google Scholar
  13. 13.
    R. W. Higgins and R. Garrett, J. Org. Chem., 27, 2168, 1962.Google Scholar
  14. 14.
    M. Hrivnac and J. Janal., Chem. Ind., 930, 1960.Google Scholar
  15. 15.
    C. H. Amberg, Can. J. Chem., 36, 590, 1958.Google Scholar
  16. 16.
    H. Prinzler and R. Hänel, Chem. Techn., 13, 439, 1961.Google Scholar
  17. 17.
    H. G. Coleman, C. G. Thompson, C. C. Ward, and H. T. Roll, Anal. Chem., 30, 1592, 1958.Google Scholar
  18. 18.
    V. I. Yakerson and L. I. Lafer, Izv. AN SSSR, Ser. khim., 611, 1965.Google Scholar
  19. 19.
    M. S. Vigdergauz and K. A. Gol'berg, Neftekhimiya, 2, 940, 1962.Google Scholar
  20. 20.
    A. B. Littlewood, C. S. G. Phillips, and D. T. Price, J. Chem. Soc., 1480, 1955.Google Scholar
  21. 21.
    Ya. L. Gol'dfarb, V. P. Litvinov, and S. A. Ozolin, KhGS [Chemistry of Heterocyclic Compounds], 663, 1965Google Scholar
  22. 22.
    D. S. Rao and B. D. Tilak, J. Sci. Ind. Res. (India), 18B, 77, 1959.Google Scholar

Copyright information

© The Faraday Press, Inc. 1966

Authors and Affiliations

  • V. I. Yakerson
    • 1
  • L. I. Lafer
    • 1
  • V. P. Litvinov
    • 1
  1. 1.Zelinskii Institute of Organic Chemistry AS USSRMoscow

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