Fresenius' Zeitschrift für analytische Chemie

, Volume 326, Issue 6, pp 495–509 | Cite as

Recent developments in atomic spectrometry methods for elemental trace determinations

  • J. A. C. Broekaert
  • G. Tölg
Review
Received:

Summary

Methods for atomic spectrometry are discussed in view of progress for elemental trace analysis and with special reference to progress in power of detection and in analytical reliability as well as with respect to economic aspects. Optical methods basing on atomic emission, absorption and fluorescence principles as well as related techniques (optogalvanic spectroscopy and coherent forward scattering), X-ray spectrometry and mass spectrometry are treated. The state-of-the-art, trends of development and new techniques such as special sample introduction for plasma spectrometry, glow discharges, laser enhanced ionization spectrometry with a thermionic diode, X-ray spectrometry with total reflection, plasma and glow discharge mass spectrometry are drawn up. Their potential interest from the point of power of detection, multielement capacity, interferences, capabilities for micro- and local analysis and speciation is compared with that of other methods for elemental analysis.

Keywords

Glow Discharge Total Reflection Elemental Trace Analysis Sample Introduction Related Technique 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Neue Entwicklungen atomspektrometrischer Methoden für die Elementspurenanalyse

Zusammenfassung

Für die atomspektrometrischen Methoden wird der Fortschritt im Hinblick auf Nachweisvermögen, analytische Zuverlässigkeit und Kosten diskutiert. Optische Methoden wie die Emissions-, Atomabsorptionsund Fluorescenzspektrometrie, aber auch verwandte Techniken (Optogalvanik und kohärente Vorwärtsstreuung), neue röntgenspektrometrische Methoden und massenspektrometrische Verfahren werden behandelt. Es werden der Stand der Technik, die Entwicklungstendenzen und neue Techniken wie spezielle Probenzuführungsmethoden für die Plasmaspektrometrie, Glimmentladungen, die laserinduzierte Ionisationsspektrometrie, die Röntgenfluorescenzspektrometrie mit Totalreflektion und der Einsatz des induktiv gekoppelten Plasmas und von Glimmentladungen als Ionenquellen für die Massenspektrometrie dargestellt. Das Nachweisvermögen, die Multielementkapazität, die Interferenzen, die Möglichkeiten für Mikro- und Verteilungsanalysen sowie für die Bestimmung der Bindungsform bei den Methoden der Atomspektrometrie werden mit denen anderer Methoden für die Bestimmung der chemischen Elemente verglichen.

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Copyright information

© Springer-Verlag 1987

Authors and Affiliations

  • J. A. C. Broekaert
    • 1
  • G. Tölg
    • 2
  1. 1.Institut für Spektrochemie und Angewandte Spektroskopie (ISAS)Dortmund 1Germany
  2. 2.Laboratorium für ReinststoffanalytikMax-Planck-Institut für Metallforschung, StuttgartDortmund 1Germany

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