Contributions to Mineralogy and Petrology

, Volume 95, Issue 3, pp 376–383 | Cite as

Reduced sapphirine granulite xenoliths from the Lace Kimberlite, South Africa; implications for the deep structure of the Kaapvaal Craton

  • J. B. Dawson
  • J. V. Smith
Article

Abstract

Sapphirine-bearing granulites, together with sapphirine-free granulites and eclogites, occur as xenoliths in the kimberlite of the Lace diatreme that penetrates the Kaapvaal craton, S. Africa. Absence of (calculated) Fe3+ in sapphirine, garnet and sillimanite, together with presence of graphite and sulphides, suggests highly reducing conditions of metamorphism. Chemical considerations and comparisons with experimental investigations suggest metamorphism of a sedimentary (?chlorite-montmorillonite) protolith at 900–1000° C and > 10 Kb; high Cr in the assemblage may point to a basic/ultrabasic precursor. The xenoliths indicate the presence of a very-high-grade granulite terrain, possibly similar to Enderby Land (Antarctica), beneath the Kaapval craton.

Keywords

Graphite Sulphide Experimental Investigation Mineral Resource Deep Structure 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Bishop FC, Smith JV, Dawson JB (1975) Pentlandite-magnetite intergrowth in De Beers spinel lherzolite: review of sulphides in nodules. Phys Chem Earth 9:323–337Google Scholar
  2. Caporuscio FA, Morse SA (1978) Occurrence of sapphirine+quartz at Peekskill, New York, Am J Sci 278:1334–1342Google Scholar
  3. Chapman DS (1986) Thermal gradients in the continental crust. In: Dawson JB, Carswell DA, Hall J, Wedepohl KH (eds) The Nature of the Lower Continental Crust, Geol Soc Lond Spec Publn 24, pp 63–70Google Scholar
  4. Chatterjee ND, Schreyer W (1972) The reaction enstatitess+sillimanite→sapphiriness+quartz in the system MgO-Al2O3- SiO2. Contrib Mineral Petrol 36:49–62Google Scholar
  5. Clifford TN (1974) Review of African granulites and related rocks. Geol Soc Am Spec Paper 156:49Google Scholar
  6. Clifford TN, Stumpfl EF, McIver JR (1975) A sapphirine-cordierite-bronzite-phlogopite paragenesis from Namaqualand, South Africa. Mineral Mag 40:347–356Google Scholar
  7. Dawson JB (1977) Sub-cratonic crust and upper-mantle models based on xenolith suites in kimberlite and nephelinitic diatremes. J Geol Soc 134:173–184Google Scholar
  8. Dawson JB (1980) Kimberlites and their xenoliths. Springer, Berlin Heidelberg New YorkGoogle Scholar
  9. Deer WA, Howie RA, Zussman J (1978) Rock-Forming Minerals, Vol 2A, Single Chain Silicates (2nd ed), Wiley, New YorkGoogle Scholar
  10. Garrels RM, Mackenzie FT (1971) Evolution of the sedimentary rocks. WW North and Co, New YorkGoogle Scholar
  11. Grew ES (1980a) Sapphirine+quartz association from Archean rocks in Enderby Land, Antarctica. Am Mineral 65:821–836Google Scholar
  12. Grew ES (1980b) Sillimanite and ilmenite from high-grade metamorphic rocks of Antarctica and other areas. J Petrol 21:39–68Google Scholar
  13. Grew ES (1982) Sapphirine, kornerupine and sillimanite+orthopyroxene in the charnockite region of south India. J Geol Soc India 23:469–505Google Scholar
  14. Griffin WL, Carswell DA, Nixon PH (1979) Lower crustal granulites and ecologites from Lesotho, southern Africa. In: Boyd FR, Meyer HOA (eds) The mantle sample: inclusions in kimberlites and other volcanics. Am Geophys Union Washington DC, pp 59–86Google Scholar
  15. Halenius U (1979) State and location of iron in sillimanite: Neues Jahrb Mineral Monatsh 1979, 165–174Google Scholar
  16. Harley SL (1985) Garnet-orthopyroxene granulites from Enderby Land, Antarctica: metamorphic pressure-temperature-time evolution of the Archaean Napier Complix. J Petrol 26:819–856Google Scholar
  17. Hart RJ, Nicolaysen LO, Gale NH (1981) Radioelement concentrations in the deep profile through Precambrian basement of the Vredefort structure. J Geophys Res 86, B11:10639–10652Google Scholar
  18. Hawkesworth CJ, Rogers NW, Van Calsteren PW, Menzies MA, Reid DL (1982) Nd- and Sr-isotope studies on crustal xenoliths from southern Africa. Terra Cognita 2:236Google Scholar
  19. Hensen BJ (1986) Theoretical phase relations involving cordierite and garnet revisited: the influece of oxygen fugacity on the stability of sapphirine and spinel in the system Mg-Fe-Al-Si-O. Contrib Mineral Petrol 92:362–367Google Scholar
  20. Higgins JB, Ribbe PH, Herd RK (1978) Sapphirine I. Crystal chemical contributions. Contrib Mineral Petrol 68:349–346Google Scholar
  21. Holdaway MJ (1979) Stability of andalusite and the aluminum silicate phase diagram. Am J Sci 271:97–131Google Scholar
  22. Lal RK, Ackermand D, Seifert F, Haldar SK (1978) Chemographic relationships in sapphirine-bearing rocks from Sonaphar, Assam, India. Contrib Mineral Petrol 67:169–187Google Scholar
  23. Lock NP (1980) The geology of the Letseng kimberlites, Lesotho. Unpubl Ph D thesis, University of SheffieldGoogle Scholar
  24. Mason R (1973) The Limpopo mobile belt, southern Africa. Philos Trans R Soc Lond A273:463–486Google Scholar
  25. Meyer HOA, Brookins DG (1976) Sapphirine, sillimanite and garnet in granulite xenoliths from Stockdale kimberlite, Kansas. Am Mineral 61:1194–1202Google Scholar
  26. Nesbitt HW (1980) Genesis of the New Quebec and Adirondack granulites: evidence for their production by partial melting. Contrib Mineral Petrol 72:303–310Google Scholar
  27. Newton RC (1972) An experimental determination of the high-pressure stability limits of magnesian cordierite under wet and dry conditions. J Geol 80:398–420Google Scholar
  28. Newton RC, Charlu TV, Kleppa OJ (1974) A calorimetric investigation of the stability of anhydrous magnesian cordierite with application to granulite facies metamorphism. Contrib Mineral Petrol 44:295–311Google Scholar
  29. Newton RC, Haselton HT (1981) Thermodynamics of the garnetplagioclase-Al2SiO5-quartz geobarometer. In: Newton RC, Navrotsky A, Wood BJ (eds) Thermodynamics of minerals and melts (Adv Phys Geochem, Vol 1): Springer, Berlin Heidelberg New York, pp 131–147Google Scholar
  30. Nixon PH, Reedman AJ, Burns LK (1973) Sapphirine-bearing granulites from Labwor, Uganda. Mineral Mag 39:420–428Google Scholar
  31. Reimer TO (1984) Graphite in Precambrian rocks of southern Africa: implications on the carbon content of metamorphic rocks. Precamb Res 26:223–234Google Scholar
  32. Reimer TO (1986) Alumina-rich rocks from the early Precambrian of the Kaapvaal craton as indicators of palaeosols and as products of other decompositional reactions. Precamb Res 32:155–179Google Scholar
  33. Rickwood PC, Mathias M, Siebert JC (1968) A study of garnets from eclogite and peridotite xenoliths found in kimberlite. Contrib Mineral Petrol 19:271–301Google Scholar
  34. Rickwood PC, Gurney JJ, White-Cooper DR (1969) The nature and occurrence of eclogite xenoliths in the kimberlites of southern Africa. Geol Soc S Afr Spec Publ 2:371–393Google Scholar
  35. Robey JVA (1981) Kimberlites of the central Cape Province RSA Unpublished Ph D thesis, University of Cape TownGoogle Scholar
  36. Sandiford M (1985) The metamorphic evolution of granulites at Fyfe Hills; implications for Archaean crustal thickness in Enderby Land, Antarctica. J Metamorphic Petrol 3:155–178Google Scholar
  37. Seifert F (1984) Stability of sapphirine: a study of the aluminous part of the system MgO-Al2O3-SiO2-H2O. J Geol 82:173–204Google Scholar
  38. Sills JD, Ackermand D, Herd RK, Windley BF (1983) Bulk composition and mineral parageneses of the sapphirine-bearing rocks along a gabbro-lherzolite contact at Finero. Ivrea Zone, N Italy. J Metamorph Geol 1:337–351Google Scholar
  39. Smith JV, Dawson JB (1975) Chemistry of Ti-poor spinels, ilmenites and rutiles from peridotite and eclogite xenoliths. Phys Chem Earth 9:309–322Google Scholar
  40. Taylor SR, McLennan SM (1985) The continental crust: its composition and evolution. Blackwell, OxfordGoogle Scholar
  41. Vallance DJ (1967) Mafic rock alteration and isochemical development of some cordierite-anthophyllite rocks. J Petrol 8:84–96Google Scholar
  42. Waters DJ, Moore JM (1985) Kornerupine in Mg-Al-rich gneisses from Namaqualand, South Africa: mineralogy and evidence for late-metamophic fluid activity. Contrib Mineral Petrol 91:369–382Google Scholar
  43. Waters DJ (1986) Metamorphic history of sapphirine-bearing and related magnesian gneisses from Namaqualand, South Africa. J Petrol 27:84–96Google Scholar
  44. Windley BF, Ackermand D, Herd RK (1984) Sapphirine/kornerupine-bearing rocks and crustal uplift history of the Limpopo belt, southern Africa. Contrib Mineral Petrol 86:342–358Google Scholar

Copyright information

© Springer-Verlag 1987

Authors and Affiliations

  • J. B. Dawson
    • 1
  • J. V. Smith
    • 2
  1. 1.Department of GeologyUniversity of SheffieldSheffieldUK
  2. 2.Department of Geophysical SciencesUniversity of ChicagoChicagoUSA

Personalised recommendations