Skip to main content
SpringerLink
Log in

A new adhesion process of glass to metal using the redox reaction

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A new adhesion process of glass to metal was developed based on the redox reaction without oxidation of the metal surface. PbO-based glasses were strongly adhered to nickel metal at low temperature (400–500 °C) in a low-oxygen atmosphere (< 0.1 p.p.m.). The interfaces between glasses and metal were analysed by SEM-EDS. It was found that the reaction layer and lead metal were formed by the redox reaction at the interface. In the case of the adhesion of PbO-based glasses containing CuO to nickel, the main reduced product in the glass was Cu2O, and lead was not detected. The redox reaction was simulated by a thermodynamic equilibrium theory; the results agreed with the analysis by SEM-EDS.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. F. Zackay, D. W. Mitchell, S. P. Mitoff and J. A. Pask, J. Am. Ceram. Soc. 36 (1953) 84.

    Article  CAS  Google Scholar 

  2. R. M. Fulrath, S. P. Mitoff and J. A. Pask, Ibid.— 40 (1957) 269.

    Article  CAS  Google Scholar 

  3. M. L. Volp, R. M. Fulrath and J. A. Pask, Ibid.— 42 (1959) 102.

    Article  Google Scholar 

  4. R. W. Cline, R. M. Fulrath and J. A. Pask, Ibid.— 44 (1961) 423.

    Article  CAS  Google Scholar 

  5. R. B. Adams and J. A. Pask, Ibid.— 44 (1961) 430.

    Article  CAS  Google Scholar 

  6. J. A. Pask and R. M. Fulrath, Ibid.— 45 (1962) 592.

    Article  CAS  Google Scholar 

  7. M. P. Borom and J. A. Pask, Ibid.— 49 (1966) 1.

    Article  CAS  Google Scholar 

  8. C. E. Hoge, J. J. Brennnan and J. A. Pask, Ibid.— 56 (1973) 51.

    Article  CAS  Google Scholar 

  9. J. J. Brennnan and J. A. Pask, Ibid.— 56 (1973) 58.

    Article  Google Scholar 

  10. K. Matusita, M. Satou, T. Komatsu and A. Nitta, in “Proceedings of the International Conference on Science and Technology of New Glass”, edited by S. Sakka and N. Soga (Ceramic Society of Japan, Tokyo, 1991) p. 163.

    Google Scholar 

  11. K. Matusita, M. Satou, T. Komatsu, T. Nakahara and A. Nitta, J. Mater. Sci. 28 (1993) 6333.

    Article  CAS  Google Scholar 

  12. H. Takashio, J. Ceram. Soc. Jpn 84 (1976) 383.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. R and D Centre, Nippon Seiki Co. Ltd., 1-190-1 Fujihashi, Nagaoka, 940-21, Niigata-ken, Japan

    H. Seki, K. Satoh & H. Satoh

  2. Department of Chemistry, Nagaoka University of Technology, 1603-1 Kamitomiokacho, Nagaoka, 940-21, Niigata-ken, Japan

    K. Matusita & R. Sato

Authors
  1. H. Seki
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Satoh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Satoh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. Matusita
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. Sato
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Seki, H., Satoh, K., Satoh, H. et al. A new adhesion process of glass to metal using the redox reaction. JOURNAL OF MATERIALS SCIENCE 31, 4891–4898 (1996). https://doi.org/10.1007/BF00355877

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00355877

Keywords

Search

Navigation