Journal of Materials Science

, Volume 30, Issue 1, pp 225–234 | Cite as

X-ray photoelectron spectroscopy and Fourier transform-infrared studies of transition metal phosphate glasses

  • E. E. Khawaja
  • S. M. A. Durrani
  • F. F. Al-Adel
  • M. A. Salim
  • M. Sakhawat Hussain
Papers
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Accepted:

Abstract

X-ray photoelectron spectroscopy and Fourier transform-infrared studies were carried out on phosphate glasses containing oxides of iron, cobalt, nickel, copper and zinc. The results suggest that the glasses containing iron and zinc may have structures in which both the phosphorus and the iron (or zinc) atoms are tetrahedrally coordinated by oxygen into three-dimensional structures which resemble the polymorphic forms of silica, whereas the glasses containing cobalt, nickel and copper may consist of polymeric chains of PO4 tetrahedra bonded to adjacent tetrahedra via bridging oxygens. These polyphosphate chains are linked together by the interaction between the metal cation and the oxygens of the network former. In addition, the core level 2p shake-up satellites of the 3d-transition metal ions in these glasses were studied. The results support a suggestion that the satellites in the glass are most likely due to the electron transfer from ligand to metal 3d orbitals.

Keywords

Zinc Cobalt Polyphosphate Core Level Phosphate Glass 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Chapman & Hall 1995

Authors and Affiliations

  • E. E. Khawaja
    • 1
  • S. M. A. Durrani
    • 1
  • F. F. Al-Adel
    • 1
  • M. A. Salim
    • 1
    • 2
  • M. Sakhawat Hussain
    • 1
    • 3
  1. 1.Energy Research Laboratory, Research InstituteKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia
  2. 2.Department of PhysicsKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia
  3. 3.Department of ChemistryKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia

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