Skip to main content
SpringerLink
Log in

Thiocyanate bond mode determination on solid manganese(II) mixed ligand coordination compounds

  • Short Communications
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Synthesized and in solid state characterized compounds correspond to the following types [Mn(NCS)2LmL'n] · x D, [Mn(NCS)2Ly]z, and [MnX2(CH3SCN)(CH3OH)] · x D (L=CH3OH or O-donors; L′=CH3SCN or N-donors; D=solvent molecules; x=0, 1 or 2; m=0, 1 or 2; n=1, 2 or 3; y=0, 1, 2, 3 or 4; z≧2; X=Cl or Br). Derivatographic investigations confirm the formation of intermediates, especially for L=H2O the existence of thermic stable partially dehydrated (“hydrate poor”) species (y=1/2 or 1/3) and μ-NCS-bonding with different ligating atoms. Solid state FT-IR analysis were carried out for band shapes, measurements of the integrated intensity, and correlations between located absorption maxima for v(CN), v(CS), δ(NCS), v(MnN), and v(MnS) and the thiocyanate bond mode.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Norbury AH (1975) Adv Inorg Chem Radiochem 17:231

    Google Scholar 

  2. Burmeister IL (1975) In: Newman AA (ed) Chemistry and biochemistry of thiocyanic acid and its derivatives. Academic Press, London

    Google Scholar 

  3. Böhland H, Samojlenko VM (1986) In: Golub AM, Köhler H, Skopenko VV (eds) Chemistry of pseudohalides. Elsevier, Amsterdam, p 239

    Google Scholar 

  4. Böhland H (1989) Wiss Z Päd Hochsch Erfurt-Mühlhausen Math Naturwiss Reihe 25:50

    Google Scholar 

  5. Böhland H, Hofmann FR, Hanay W, Berner HJ (1989) Z Anorg Allg Chem 577:53

    Google Scholar 

  6. Böhland H, Witzenhausen U (1991) Z Anorg Allg Chem 600:131

    Google Scholar 

  7. Flint CD, Goodgame M (1970) J Chem Soc A:442

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Chemie, Pädagogische Hochschule Erfurt-Mühlhausen, Schillerweg 59, D-99974, Mühlhausen, Germany

    H. Böhland, G. König, I. Berg & H. Umbreit

Authors
  1. H. Böhland
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. König
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. Berg
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Umbreit
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Böhland, H., König, G., Berg, I. et al. Thiocyanate bond mode determination on solid manganese(II) mixed ligand coordination compounds. Fresenius J Anal Chem 349, 228–230 (1994). https://doi.org/10.1007/BF00323288

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00323288

Keywords

Search

Navigation