Polymer Bulletin

, Volume 32, Issue 3, pp 273–279 | Cite as

Synthesis of porous poly(hydroxamic acid) from poly(ethyl acrylate-co-divinylbenzene)

  • Taek Seung Lee
  • Sung HongII
Article

Summary

Porous poly(hydroxamic acid) resins were prepared by suspension polymerization of poly(ethyl acrylate-co-divinylbenzene) followed by the reaction with hydroxylamine via nucleophilic substitution. Various degree of dilution and crosslinking ratio were applied to obtain suitable material for use as a chelating polymer. The effects of degree of dilution and crosslinking ratio on the surface morphology, hydroxamic acid group content, and apparent density were investigated in detail.

Keywords

Polymer Ethyl Surface Morphology Material Processing Acid Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Kern W, Schulz RC (1957) Angew Chem 69: 153Google Scholar
  2. 2.
    Crumbliss AL, Garrison JM (1987) Inorg Chim Acta 133: 281Google Scholar
  3. 3.
    Petrie G, Locke D, Meloan CE (1965) Anal Chem 37: 919Google Scholar
  4. 4.
    Schouteden F (1958) Makromol Chem 27: 246Google Scholar
  5. 5.
    USP 4,868,248 (1989)Google Scholar
  6. 6.
    Domb J, Cravalho EG, Langer R (1988) J Polym Sci Polym Chem Ed 26: 2623Google Scholar
  7. 7.
    Vernon F, Eccles H (1975) Anal Chim Acta 77: 145Google Scholar
  8. 8.
    Vernon F (1982) Pure Appl Chem 54: 2151Google Scholar
  9. 9.
    Vernon F, Eccles H (1981) Anal Chim Acta 123: 309Google Scholar
  10. 10.
    Jeffery GH, Basett J, Mendham J, Denney RC (1989) Textbook of Quantitative Chemical Analysis. Longman Scientific & TechnicalGoogle Scholar
  11. 11.
    Krause A, Lange A, Ezrin M (1983) Plastics Analysis Guide. Hanser PublishersGoogle Scholar
  12. 12.
    Brunauer S, Emmett P, Teller E (1938) J Am Chem Soc 60: 309Google Scholar
  13. 13.
    Kolarz BN, Trochimczuk A, Bryjak J, Wojaczynska M, Dziegielewski K, Noworyta A (1990) Angew Makromol Chem 179: 173Google Scholar
  14. 14.
    Alkelah A, Selim A, El-Hamshary H (1988) Eur Polym J 24: 1111Google Scholar
  15. 15.
    Hassanein M, Aly EA, Abbas YA, El-Sigeny M (1992) Eur Polym J 28: 411Google Scholar
  16. 16.
    Skovby MHB, Kops J (1990) J Appl Polym Sci 39: 169Google Scholar
  17. 17.
    Colthup NB, Daly LH, Wiberley SE (1975) Introduction to infrared and raman spectroscopy. Academic PressGoogle Scholar
  18. 18.
    Seidl J, Marinsky J, Dusek K, Heitz W (1967) Adv Polym Sci 5: 113Google Scholar

Copyright information

© Springer-Verlag 1994

Authors and Affiliations

  • Taek Seung Lee
    • 1
  • Sung HongII
    • 1
  1. 1.Department of Fiber and Polymer Science, College of EngineeringSeoul National UniversitySeoulKorea

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