Polymer Bulletin

, Volume 5, Issue 11–12, pp 577–584

Structure investigation of organosilicon polymers by silicon-29 NMR

  • G. Engelhardt
  • H. Jancke


High resolution silicon-29 NMR is used to study the microstructure of organosiloxane chain copolymers and three-dimensional cross-linked silicone resins. The signal splittings of the Si-29 NMR spectra of methy1-pheny1 siloxane copolymers have been assigned to monomer sequences up to the pentad level and the quantitative microstructure parameters have been estimated. It is shown that Si-29 NMR offers valuable information on the polymer framework of silicone resins both in the liquid and in the solid state.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. ENGELHARDT, G., JANCKE, H., LIPPMAA, E. and SAMOSON, A.: J.Organometal.Chem. 210, 295 (1981)Google Scholar
  2. ENGELHARDT, G., MÄGI, M. and LIPPMAA, E.: J.Organometal.Chem. 54, 115 (1973)Google Scholar
  3. HARRIS, R.K.: NMR and the Periodic Table, London, New York: Academic Press 1979Google Scholar
  4. HARRIS, R.K. and KIMBER, B.J.: J.Organometal.Chem. 70. 43 (1974)PubMedGoogle Scholar
  5. HARRIS, R.K. and KIMBER, B.J.: Appl.Spectros. 10, 117 (1975)Google Scholar
  6. HARRIS, R.K. and ROBINS, M.L.: POLYMER 19, 1123 (1978)Google Scholar
  7. HARWODD, H.J. and RITCHEY, W.M.: J.Polymer.Sci.B, Polymer Letters 2, 601 (1964)Google Scholar
  8. JANCKE, H., ENGELHARDT, G., KRIEGSMANN, H. and KELLER, F.: Plaste und Kautschuk 26, 612 (1979)Google Scholar

Copyright information

© Springer-Verlag 1981

Authors and Affiliations

  • G. Engelhardt
    • 1
  • H. Jancke
    • 1
  1. 1.Central Institute of Physical ChemistryAcademy of Sciences of the GDRBerlinGerman Democratic Republic

Personalised recommendations