Polymer Bulletin

, Volume 5, Issue 11, pp 577–584

Structure investigation of organosilicon polymers by silicon-29 NMR

  • G. Engelhardt
  • H. Jancke

DOI: 10.1007/BF00255295

Cite this article as:
Engelhardt, G. & Jancke, H. Polymer Bulletin (1981) 5: 577. doi:10.1007/BF00255295


High resolution silicon-29 NMR is used to study the microstructure of organosiloxane chain copolymers and three-dimensional cross-linked silicone resins. The signal splittings of the Si-29 NMR spectra of methy1-pheny1 siloxane copolymers have been assigned to monomer sequences up to the pentad level and the quantitative microstructure parameters have been estimated. It is shown that Si-29 NMR offers valuable information on the polymer framework of silicone resins both in the liquid and in the solid state.

Copyright information

© Springer-Verlag 1981

Authors and Affiliations

  • G. Engelhardt
    • 1
  • H. Jancke
    • 1
  1. 1.Central Institute of Physical ChemistryAcademy of Sciences of the GDRBerlinGerman Democratic Republic

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