Abstract
The spectroelectrochemical behaviour of cast poly(3-octylthiophene) (POT) films (0.2 and 0.5 μm) on indium-tin-oxide (ITO) glass electrodes has been investigated in organic media. These thin films exhibit interesting electrochromic properties and their application in electrochromic devices has been examined in liquid (CH3CN + LiClO4 0.3 M) and viscous electrolyte (PEO + CH3CH + LiClO4). Polyaniline (PANI) film appears to be a convenient complementary counter electrode since its transmission maximum corresponds to its oxidized state and that of POT film to its reduced state. Thin films of iridium oxide (IrO2) are also possible counter electrodes, even in acetonitrile, the electrochemical behaviour being mostly capacitive with a low transmission change. However, the best contrast is obtained with the POT/PANI system.
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References
M. Sato, S. Tanaka, K. Kaeriyama and F. Tomonaga, Polymer 28 (1987) 1071.
S. Panero, P. Prosperi, B. Klapste and N. Scrosati, Electrochimica Acta 31 (1986) 1597.
M. Gazard, J. C. Dubois, M. Champagne, F. Garnier and G. Tourillon, J. Phys. Chem. 44 (1983) C3–537.
M. Gazard, F. Garnier and G. Tourillon, European Patent 83 401 026.6. (1983).
F. Garnier, G. Tourillon, M. Gazard and J. C. Dubois, J. Electroanal. Chem. 148 (1983) 299.
M. Mastragostino, C. Arbizzano, A. Bongini, G. Barbarella and M. Zambianchi, Electrochimica Acta 38 (1993) 135.
H. B. Gu, S. Nakajima, R. Sugimito and K. Yoshino, Jpn. J. Appl. Phys. 27 (1988) 311.
J. Roncali, Chem. Rev. 92 (1988) 711.
R. D. Raugh, ‘Variable Transmittance Electrochromic Windows’. Proceeding of the Passive and Hybrid Solar Energy Update, Washington, DC, USA (November 1983) p. 225.
E. M. Genies, A. Boyle, M. Lapkowski and C. Tsintavis, Synth. Met. 36 (1990) 139.
E. M. Genies, M. Lapkowski, P. Noël, S. Langlois, M.-N. Collomb and F. Miquelino, ibid. 41 (1991) 2847.
G. A. Gruver and T. Kuwana, J. Electroanal. Chem. 36 (1972) 85.
K. Yoshino, S. Nakajima, M. Fuji and R. Sugimito, Polym. Commun. 28 (1987) 309.
W. Buchner, R. Garreau, M. Lemaire and F. Garnier, J. Electroanal. Chem. 277 (1990) 355.
G. Bidan, E. M. Genies and J.-F. Penneau, ibid. 271 (1989) 59.
N. Leventis and Y. C. Chung, Chem. Mater. 4 (1992) 1415.
Y. Sato, Jpn. J. Appl. Phys. 28 (1989) 1290.
J. D. E. McIntyre, S. Basu, W. F. Peck, W. L. Brown and W. M. Augustyniak, Phys. Rev. B 25 (1982) 7242.
T. Nguyen and L. H. Dao, J. Electrochem. Soc. 136 (1989) 2131.
B. P. Jelle, G. Hagen and R. Ødegard, Electrochim. Acta 37 (1992) 1377.
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Collomb-Dunand-Sauthier, MN., Langlois, S. & Genies, E. Spectroelectrochemical behaviour of poly (3-octylthiophene): application to electrochromic windows with polyaniline and iridium oxide. J Appl Electrochem 24, 72–77 (1994). https://doi.org/10.1007/BF00243332
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DOI: https://doi.org/10.1007/BF00243332