Journal of Biomolecular NMR

, Volume 8, Issue 2, pp 161–170 | Cite as

PLUSH TACSY: Homonuclear planar TACSY with two-band selective shaped pulses applied to Cα,C′ transfer and Cβ,Caromatic correlations

  • T. Carlomagno
  • M. Maurer
  • M. Sattler
  • M. G. Schwendinger
  • S. J. Glaser
  • C. Griesinger
Research Papers

Summary

A new homonuclear Hartmann-Hahn-type mixing scheme is introduced that effects coherence transfer between resonances in two separated frequency bands. The mixing scheme relies on the irradiation of two-band selective shaped pulses that are expanded in an MLEV-16 supercycle. Similar to heteronuclear Hartmann-Hahn experiments, a planar effective coupling tensor is created. This novel mixing scheme is applied to Cα,C′ transfer and to the transfer between Cβ and aromatic carbon spins.

Keywords

PLUSH TACSY HEHAHA HOHAHA Band-selective coherence transfer Sensitivity enhancement 

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Copyright information

© ESCOM Science Publishers B.V 1996

Authors and Affiliations

  • T. Carlomagno
    • 1
  • M. Maurer
    • 1
  • M. Sattler
    • 1
  • M. G. Schwendinger
    • 1
  • S. J. Glaser
    • 1
  • C. Griesinger
    • 1
  1. 1.Institute of Organic ChemistryUniversity of FrankfurtFrankfurtGermany

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