Mineralium Deposita

, Volume 7, Issue 1, pp 13–17 | Cite as

Textural and chemical evidence bearing on sulfide-silicate reactions in metasediments

  • W. J. Mallio
  • M. A. Gheith
Article

Abstract

Two textural relationships between pyrrhotite and ferromagnesian silicates were found to occur in a metamorphosed sandy pelite at the staurolite grade of metamorphism. (1) Increased grain size of silicates at the pyrrhotite-silicate boundary; (2) Oriented intergrowths of pyrrhotite in large grains of chlorite and biotite. Both textures were interpreted as resulting from sulfide-silicate reactions. Ferromagnesian silicates in these sulfidic rocks show higher Mg/Fe ratios than those in non-sulfidic rocks in the same area.

Keywords

Grain Size Mineral Resource Chemical Evidence Textural Relationship Ferromagnesian Silicate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Zusammenfassung

In einem bis zur Staurolith-Fazies metamorphosierten ehemaligen sandigen Pelit werden zwei Gefügebeziehungen zwischen Magnetkies und Eisen-Magnesium-Silikaten festgestellt: (1) Eine Kornvergrößerung der Silikate an der Grenze Magnetkies—Silikate; (2) Eine orientierte Verwachsung von Magnetkies mit großen Kristallen von Chlorit und Biotit. Beide Gefüge werden als Reaktionsgefüge zwischen Sulfiden und Silikaten gedeutet. Die Eisen-Magnesium-Silikate zeigen in diesen Gesteinen reich an Sulfiden höhere Mg/Fe-Verhältnisse als in sulfidfreien Gesteinen desselben Gebietes.

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References

  1. Antun, P.: Sedimentary Pyrite and its Metamorphism in the Oslo Region. Norsk Geol. Tidsskr. 47, 211–235 (1967).Google Scholar
  2. Colby, J. W.: The Applicability of Theoretically Calculated Intensity Corrections in Microprobe Analysis. In: The Electron Microprobe, pp. 95–188. New York: John Wiley & Sons, Inc 1966.Google Scholar
  3. Desborough, G. A., Carpenter, R. H.: Phase Relations of Pyrrhotite. Econ. Geol. 60, 1431 (1965).Google Scholar
  4. Froese, E.: Metamorphic rocks from the Coronation Mine and Surrounding Area. G. S. C. Paper 68–5, 55–77 (1969).Google Scholar
  5. —: The Graphical Representation of Sulfide-Silicate Phase Equilibria. Econ. Geol. 66, 335–341 (1971).Google Scholar
  6. Fullager, P. D., Brown, H. S., Hagner, A. F.: Geochemistry of Wall Rock Alteration and the Role of Sulfurization in the Formation of the Ore Knob Sulfide Deposit. Econ. Geol. 62, 798–825 (1967).Google Scholar
  7. George, R. J.: Sulphide-Silicate Reactions During Metamorphism of the Nairne Pyrite Deposit. Proc. Australasian Inst. Mining Met. 230, 1–7 (1969).Google Scholar
  8. Guidotti, C. V.: The Mineralogy and Petrology of the Transition from the Lower to Upper Sillimanite Zone in the Oquossoc Area, Maine. J. Petrol. 11, 277–336 (1970).Google Scholar
  9. Kinkel, A. R. Jr.: The Knob Copper Deposit, N. C., and Other Massive Sulfide Deposits of the Appalachians. U. S. Geol. Surv., Profess. Papers 558, 1–58 (1967).Google Scholar
  10. Kullerud, G., Yoder, Jr., H. S.: Sulfide-Silicate Relations, Annual Report of the Director of the Geophysical Laboratory, 1962–63. Carnegie Inst. Wash., Yearbook 62, 215–218 (1963).Google Scholar
  11. — Sulfide-Silicate Reactions, Annual Report of the Director of the Geophysical Laboratory 1963–64. Carnegie Inst. Wash., Yearbook 63, 218–222 (1964).Google Scholar
  12. Mallio, W. J., Carter, J. R., Binnie, W. P.: An Improved X-ray Method for the Determination of Pyrrhotite Composition (in preparation).Google Scholar
  13. McDonald, J. A.: Metamorphism and Its Effects on Sulfide Assemblages. Mineral Deposita (Berl.) 2, 200–220 (1967).Google Scholar
  14. Moench, R. H.: Geology of the Phillips Quadrangle, Ph. D. thesis, Boston University, Boston, Massachusetts, 230 p., 1954.Google Scholar
  15. Mookherjee, A., Suffel, G. G.: Massive Sulfide — Late Diabase Relationships, Horne Mine, Quebec: Genetic and Chronological Implications. Can. J. Earth Sci. 5, 421–32 (1968).Google Scholar
  16. Naldrett, A. J., Kullerud, G.: Investigations of the Nickel-Copper Ores and Adjacent Rocks of the Sudbury District, Ontario. Annual Report of the Director of the Geophysical Laboratory, 1964–65. Carnegie Inst. Wash., Yearbook 64, 177–188 (1965).Google Scholar
  17. Neumann, H.: Pseudomorphs of Pyrrhotine After Pyrite in the Ballachulish Slates, Mineral. Mag. (London) 210, 234–238 (1950).Google Scholar
  18. Osberg, R. H., Moench, R. H., Warner, J.: Stratigraphy of the Merrimack Synclinorium in West-Central Maine. In: Studies in Appalachian Geology-Northern and Maritime (Billings Volume), pp. 241–266. New York: John Wiley and Sons 1968.Google Scholar
  19. Skinner, B., J.: The Geology and Metamorphism of the Nairne Pyritic Formation, A Sedimentary Sulfide Deposit in South Australia. Econ. Geol. 55, 546–562 (1958).Google Scholar
  20. Stevenson, J. S.: Mineralization and Metamorphism at the Eustis Mine Quebec. Econ. Geol. 32, 335–363 (1937).Google Scholar
  21. Vokes, F. M.: Regional Metamorphism of the Paleozoic Geosynclinal Sulphide Ore Deposits of Norway. Inst. Min. Met. Trans. Sec. B. 77, B53–59 (1968).Google Scholar
  22. — A Review of the Metamorphism of Sulphide Deposits. Earth-Sci. Rev. 5, 99–143 (1969).Google Scholar
  23. — Discussion: Aspects of Wall Rock Alteration Associated with some Finnish Sulfide Deposits: A Review (by) A. K. Mikkola. Inst. Min. Met. Trans. Sec. B. 79, 99–100 (1970).Google Scholar

Copyright information

© Springer-Verlag 1972

Authors and Affiliations

  • W. J. Mallio
    • 1
  • M. A. Gheith
    • 1
  1. 1.BostonUSA

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