Phosphate adsorption on bottom sediments of the Rio de la Plata
- 44 Downloads
- 4 Citations
Abstract
A study of the phosphate adsorption onto the bottom sediments of the Rio de la Plata has been made with the aim to understand the dynamics of this compound in the fluvio-marine system. Previous to the chemical analysis of the phosphate content, an extraction of the different adsorbed phosphate fractions have been made. In addition to phosphate, calcium, iron and aluminium in the sediment samples were determined. The phosphate is associated to the fine fractions of the sediments and good correlations with Al and Fe content in the bottom sediments were found. There is a relative decrease of the adsorbed phosphate on the bottom sediment in the areas where the influence of the marine water is more conspicuous; it is explained by the pH increase of the estuary waters due to the mixture with the marine waters. A hypothesis about the role of the ionic strength and the pH on the phosphate adsorption process is suggested.
Key words
phosphate adsorption aluminium iron calcium sediments Rio de la PlataPreview
Unable to display preview. Download preview PDF.
References
- Balay, M., 1962. El Rio de la Plata Pub. H. S. Hidrog. Naval, Buenos Aires, Argentina. 58 pp.Google Scholar
- Bostrom, B., 1984. Potential mobility of Phosphorous in different types of lakes sediments. Int. Revue ges. Hydrobiol 69: 457–474.Google Scholar
- Carreto, J. I., R. Negri & H. R. Benavides, 1986. Algunas caracteristicas del florecimiento del fitoplancton en el frente del Rio de la Plata. I: Sistemas nutritivos. Rev. Inves. Des. Pesq. 5: 7–29.Google Scholar
- Hayes, F. R. & J. E. Phillips, 1958. Lake water and sediment: IV Radiophosphorus equilibrium with mud, plants and bacter under oxidized and reduced conditions. Limnol. Oceanogr. 3: 459–475.Google Scholar
- Hieltjes, A. H. M. & L. Lijklema, 1980. Fractionation of inorganic phosphates on calcareous sediments. J. Envir. Qual. 9: 405–407.Google Scholar
- Lanfredi, N. W., T. Schmidt & J. O. Speroni, 1979. Cartas de Corrientes de Marea Rio de la Plata. Informe tecnico, Ser. Hidrog. Naval Dto. Oceanografia, IC-IT/79–03.Google Scholar
- Maine, M. A., J. A. Hammerly, M. S. Leguizamon & M. J. Pizarro, 1992. Influence of the pH and redox potential on phosphate activity in the Parana Medio system. Hydrobiologia 228: 83–90.Google Scholar
- Murphy, J. & J. Riley, 1962. A modified single solution method for the determination of phosphate in natural waters. Anal. Chim. Acta 27: 31–36.Google Scholar
- Nagy, G., 1983. Caracterizacion de los Procesos hidrologicos del Rio de la Plata. Tesis para optar al titulo de ‘Licenciado en Oceanografia’ F. Humanidades y Ciencias. Universidad de la Republica — R.O. Uruguay.Google Scholar
- Nur, R. & M. Bates, 1979. The effects of pH on the aluminium, iron and calcium phosphate fractions of lake sediments. Wat. Res. 13: 813–815.Google Scholar
- Ottmann, F. & C. M. Urien, 1965. Le melange des Eaux douces et marines dans le Rio de la Plata. Cah. Oceanogr. 7: 703–713.Google Scholar
- Ottmann, F. & C. M. Urien, 1966. Sur quelques problems sedimentologiques dans le Rio de la Plata. Rev. Geogr. Phys. Geolg. Dynam. 8: 209–224.Google Scholar
- Parker, G., J. Marcolini, J. Cavalotto & R. Violante, 1987. Modelo esquematico de dispersion de sedimentos en el Rio de la Plata. Cienc. Tecnol. Agua 1: 68–80.Google Scholar
- Pizarro, M. J. & A. Orlando, 1984. Distribucion de fosforo, nitrogeno y silicio disueltos en el Rio de la Plata. Ser. Hidr. Naval, Publ. H. 625, 57 pp.Google Scholar
- Siegel, F. R., J. W. Pierce, J. M. Urien & I. C. Stone, 1968. Clay Mineralogy in the Estuary of the Rio de la Plata, South America. XXIII International Geological Congress, Prague, 8: 32–37.Google Scholar
- Stumm, W. & J. J. Morgan, 1970. Aquatic Chemistry. Wiley-Interscience, 583 pp, New York.Google Scholar
- Tossini, L., 1959. Sistema Hidrografico y Cuenca del Rio de la Plata. Anales Soc. Cient. Argentina, Buenos Aires. 112 pp.Google Scholar
- Urien, J. M., 1966. Distribucion de los sedimentos en el Rio de la Plata superior. Bol. Ser. Hidrog. Naval III: 197–203.Google Scholar
- Urien, J. M., 1972. Rio de la Plata Estuary environment. The Geological Soc. Am., Inc. Memoir 133: 213–234.Google Scholar