Skip to main content
SpringerLink
Log in

Electrical Conductivity and Dielectric Permittivity of γ-Irradiated Nanocomposites Based on Ultrahigh-Molecular-Weight Polyethylene Filled with α-SiO2

  • Published:
Surface Engineering and Applied Electrochemistry Aims and scope Submit manuscript

Abstract

UHMWPE/SiO2 composites were obtained from a homogeneous mixture of ultrahigh-molecular- weight polyethylene (UHMWPE) and silicon dioxide (α-SiO2) by hot pressing. The temperature dependence (20–170°C) of their conductivities σdс prior to and after γ irradiation (D = 200 kGy), the effect of absorbed dose on the σdс value (dose dependence), the behavior of the function logσdc = f(T) under heating–cooling conditions, and the frequency dependences (25–106 Hz) of the real (ε') and imaginary (ε'') parts of the complex dielectric constant were studied. The logσdc = f(T) dependence was shown to have in both cases a complex pattern: “breaks” due to phase transitions were observed. With an increase in the concentration of α-SiO2, the ε' and ε'' (tanδ) values in the matrix increased and the frequency dependences of these values corresponded to an exponential rule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Chmutin, I.A., Ryvkina, N.G., Solov’eva, A.B., Kedrina, N.F., Timofeeva, V.A., Rozhkova, N.N., and McQueen, D.H., Polym. Sci., Ser. A, 2004, vol. 46, no. 6, pp. 664–671.

    Google Scholar 

  2. Meshkova, I.N., Krasheninnikov, V.G., Optov, V.A., Gavrilov, Y.A., Silkina, E.N., and Pletneva, I.V. Polym. Sci., Ser. A, 2014, vol. 56, no. 5, pp. 646–651.

    Article  Google Scholar 

  3. Ramanatham, T., Stankovich, S., Dikin, D.A., Liu, H., et al., J. Polym. Sci., Part B: Polym. Phys., 2007, vol. 45, pp. 2097–2112.

    Article  Google Scholar 

  4. Tyutnev, A.P., Saenko, V.S., Pozhidaev, E.D., and Kostyukov, N.S., Dielektricheskie svoistva polimerov v polyakh ioniziruyushchikh izluchenii (Dielectric Properties of Polymers in Fields of Ionizing Radiation), Moscow: Nauka, 2005.

    Google Scholar 

  5. Guo, N., DiBenedetto, S.A., Tewari, P., Lanagan, M.T., et al., Chem. Mater., 2010, vol. 22, no. 4, pp. 1567–1578.

    Article  Google Scholar 

  6. Gorokhovatskii, Yu.A., Tazenkov, B.A., Aniskina, L.B., Chistyakova, O.V., et al., Izv. Ross. Gos. Pedagog. Univ. im. A.I. Gertsena, 2009, (95), 63–66.

    Google Scholar 

  7. Yang, D., Advances in Nanocomposites-Synthesis, Characterization and Industrial Applications, Boreddy, S.R., Ed., Rijeka: InTech, 2011, pp. 857–882.

  8. Gefle, O.S., Lebedev, S.M., and Pokholkov, Yu.P., Izv. Tomsk. Politekh. Univ., 2007, vol. 310, no. 1, pp. 87–91.

    Google Scholar 

  9. Gordienko, V.P., Radiatsionnoe modifitsirovanie kompozitsionnykh materialov na osnove poliolefinov (Radiation Modification of Composites Based on Polyolefins), Kiev: Naukova Dumka, 1986.

    Google Scholar 

  10. Gordienko, V.P., Vampirov, Yu.M., and Kovaleva, G.N., Plast. Massy, 2008, no. 4, pp. 6–8.

    Google Scholar 

  11. Magerramov, A.M., Strukturnoe i radiatsionnoe modifitsirovanie elektretnykh, p’ezoelektricheskikh svoistv polimernykh kompozitov (Structural and Radiation Modification of Electret and Piezoelectric Properties of Polymeric Composites), Baku: Elm, 2001.

    Google Scholar 

  12. Kuliev, M.M., Magerramov, A.M., Ismaiilova, R.S., and Nabiev, A.A., Perspekt. Mater., 2015, no. 7, pp. 17–22.

    Google Scholar 

  13. Andreeva, I.N., Veselovskaya, E.V., Nalivaiko, E.I., et al., Sverkhvysokomolekulyarnyi polietilen vysokoi plotnosti (Ultra-High Molecular Dense Polyethylene), Leningrad: Khimiya, 1982.

    Google Scholar 

  14. Selyutin, G.E., Gavrilov, Yu.Yu., Voskresenskaya, E.N., Zakharov, V.A., Nikitin, V.E., and Poluboyarov, V.A., Chem. Sustainable Dev., 2010, vol. 18, no. 3, pp. 375–388.

    Google Scholar 

  15. Kulivev, M.M. and Ismayilova, R.S., Surf. Eng. Appl. Electrochem., 2010, vol. 46, no. 5, pp. 447–451.

    Article  Google Scholar 

  16. Vannikov, A.V., Matveev, V.K., Sichkar’, V.P., and Tyutnev, A.P., Radiatsionnye effekty v polimerakh. Elektricheskie svoistva (Radiation Effects in Polymers. Electric Properties), Moscow: Nauka, 1982.

    Google Scholar 

  17. Ul’zutuev, A.N. and Ushakov, N.M., Tech. Phys. Lett., 2011, vol. 37, no. 2, pp. 95–97.

    Article  Google Scholar 

  18. Ul’zutuev, A.N., Ushakov, N.M., Yurkov, G.Yu., and Kosobudskii, I.D., Tech. Phys. Lett., 2009, vol. 35, no. 5, pp. 476–478.

    Article  Google Scholar 

  19. Radwan, R.M., Aly, S.S. and Abd El Aal, S., J. Radiat. Res. Appl. Sci., 2008, vol. 11, pp. 9–16.

    Google Scholar 

  20. Kuliev, M.M. and Ismaiilova, R.S., Surf. Eng. Appl. Electrochem., 2009, vol. 45, no. 4, pp. 297–299.

    Article  Google Scholar 

  21. Moskalyuk, O.A., Aleshin, A.N., Tsobkallo, E.S., Krestinin, A.V., and Yudin, V.E., Phys. Solid State, 2012, vol. 54, no. 10, pp. 2122–2127.

    Article  Google Scholar 

  22. Gordienko, V.P. and Sal’nikov, V.G., Plast. Massy, 2014, nos. 5–6, pp. 9–13.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Radiation Problems, Azerbaijan National Academy of Sciences, Baku, Az-1143, Republic of Azerbaijan

    R. S. Ismaiilova, A. M. Magerramov & M. M. Kuliev

  2. Azerbaijan State Marine Academy, Baku, Az-1000, Republic of Azerbaijan

    G. A. Akhundova

Authors
  1. R. S. Ismaiilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. M. Magerramov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. M. Kuliev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Akhundova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. S. Ismaiilova.

Additional information

Original Russian Text © R.S. Ismaiilova, A.M. Magerramov, M.M. Kuliev, G.A. Akhundova, 2017, published in Elektronnaya Obrabotka Materialov, 2017, No. 3, pp. 12–18.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ismaiilova, R.S., Magerramov, A.M., Kuliev, M.M. et al. Electrical Conductivity and Dielectric Permittivity of γ-Irradiated Nanocomposites Based on Ultrahigh-Molecular-Weight Polyethylene Filled with α-SiO2. Surf. Engin. Appl.Electrochem. 54, 6–11 (2018). https://doi.org/10.3103/S1068375518010076

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068375518010076

Keywords

Search

Navigation