Abstract
The solvation effects that arise on dissolving an ionizing impurity or with charge injection into a nonpolar liquid dielectric are considered. The polarization energy of solvation is calculated for the continuum approximation in a boundless fluid and near the metal surface.
Similar content being viewed by others
References
Zhdanov, S.I. and Gracheva, N.P., Elektrokhimiya zhidkikh kristallov. Zhidkie kristally (Electrochemistry of Liquid Crystals. Liquid Crystals), Moscow: Khimiya, 1979.
Fialkov, Yu.Ya, Zhitomirskii, A.N., and Tarasenko, Yu.A., Fizicheskaya khimiya nevodnykh rastvorov (Physical Chemistry of NonAqueous Solutions), Leningrad: Khimiya, 1973.
Krestov, G.A., Termodinamika ionnykh protsessov v rastvorakh (Thermodynamics of Ion Processes in Solutions), Leningrad: Khimiya, 1984.
Fialkov, Yu.Ya, Rastvoritel’ kak sredstvo upravleniya khimicheskim processom (Solvent as Means to Control a Chemical Process), Leningrad: Khimiya, 1990.
Goronovskii, I.T., Nazarenko, Yu.P., and Nekryach, E.F., Kratkii spravochnik po khimii (Short Chemistry Reference Book), Kiev: Naukova Dumka, 1974.
Tomilov, A.G., Mairanovskii, S.G., Fioshin, M.N., and Smirnov, V.A., Elektrokhimiya organicheskikh soedinenii (Electrochemistry of Organic Compounds), Leningrad: Khimiya, 1968.
Izmailov, N.A., Elektrokhimiya rastvorov (Electrochemistry of Solutions), Moscow: Khimiya, 1976.
Belousov, V.P. and Morachevskii, A.G., Teploty smesheniya zhidkostei (Heats of Liquid Mixing), Moscow: Khimiya, 1970.
Zhakin, A.I., Ionic conduction and complexation in liquid dielectrics, Phys. Usp., 2003, vol. 46, no. 1, pp. 45–61.
Zhakin, A.I., Near-electrode and transient processes in liquid dielectrics, Phys. Usp., 2006, vol. 49, no. 3, pp. 275–295.
Drago, R., Physical Methods in Chemistry, New York: W.B. Saunders Company, 1977.
Kalugin, O.N., Kolesnik, Ya.V., and Volobuev, V.N., Microstructure and dynamics of particles in ionmolecular systems based on acetonitrile, dimethyl sulfoxide and methanol: Molecular dynamics simulation, in Nauchnoe nasledie N.A. Izmailova i aktual’nye problemy fizicheskoi khimii (Scientific Heritage of N.A. Izmailov and Current Problems of Physical Chemistry), Kharkov: Kharkov National University, 2007, pp. 403–533.
Simkin, B.Ya. and Sheikhet, I.I., Kvantovokhimicheskaya i statisticheskaya teoriya rastvorov. Vychislitel’nye metody i ikh primenenie (Quantum Chemical and Statistical Theory of Solutions. Computation Methods and Application), Moscow: Khimiya, 1989.
Burger, K., Solvation, Ionic and Complex Formation Reactions in NonAqeuous Solvents, Amsterdam: Elsevier, 1983.
Gordon A. and Ford R., The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, New York: Willey, 1972.
Shakhparonov, M.I., Vvedenie v sovremennuyu teoriyu rastvorov (Introduction to Modern Theory of Solutions), Moscow: Vysshaya Shkola, 1976.
Krestov, G.A., Novoselov, N.P., and Perelygin, I.S., Ionnaya sol’vatatsiya (Ion Solvation), Moscow: Nauka, 1987.
Tamm, I.E., Osnovy teorii elektrichestva (Theoretical Foundations of Electricity), Moscow: Fizmatlit, 2003.
Dobretsov, L.N. and Gomoyunova, M.V., Emissionnaya elektronika (Emission Electronics), Moscow: Nauka, 1966.
Shikin, V.B. and Monarkha, Yu.P., Dvumernye zaryazhennye sistemy v gelii (Two-Dimensional Charged Systems in Helium), Moscow: Nauka, 1989.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.I. Zhakin, 2015, published in Elektronnaya Obrabotka Materialov, 2015, No. 6, pp. 32–42.
About this article
Cite this article
Zhakin, A.I. Solvation effects in liquid dielectrics. Surf. Engin. Appl.Electrochem. 51, 540–551 (2015). https://doi.org/10.3103/S1068375515060125
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1068375515060125