Abstract
The electrodeposition of iron and composite iron-zirconia coatings from a methanesulfonate electrolyte was investigated. The current efficiency of iron deposition reaction was stated to be sufficiently higher in methanesulfonate electrolytes than in usual sulfate baths. Iron coatings electrodeposited from a methanesulfonate bath have a nanocrystalline structure. The Fe coatings obtained from methanesulfonate baths are harder than those deposited from sulfate baths because of the strengthening effect by the Hall-Petch mechanism. The composite Fe/ZrO2 coatings can be obtained from the iron electroplating baths containing the particles of zirconia stabilized by 3 mol % yttria. The kinetics of ZrO2 particles co-deposition with iron in methanesulfonate electrolytes obeys Guglielmi’s model. The insertion of zirconia particles into the iron matrix results in an appreciable increase of the coatings microhardness via the dispersion strengthening mechanism.
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Díaz, S.L., Calderón, J.A., Barcia, O.E., and Mattos, O.R., Electrodeposition of iron in sulphate solutions, Electrochim. Acta, 2008, vol. 53, pp. 7426–7435.
Panayotova, M., Deposition of Fe-C alloy on structural steel and cast iron for repair of worn machine parts, Surf. Coat. Technol., 2000, vol. 124, pp. 266–271.
Miyamoto, N., Yoshida, K., Matsuoka, M., and Tamaki, J., Effect of phosphorus content on mechanical properties of electrodeposited Fe-C-P alloys, J. Electrochem. Soc., 2004, vol. 151, pp. C645–C648.
Lallemand, F., Ricq, L., Wery, M., Berçot, P., and Pagetti, J., The influence of organic additives on the electrodeposition of iron-group metals and binary alloy from sulfate electrolyte, Appl. Surf. Sci., 2004, vol. 228, pp. 326–333.
Danilov, F.I., Protsenko, V.S., and Ubiikon’, A.V., Kinetic regularities governing the reaction of electrodeposition of iron from solutions of citrate complexes of iron(III), Russ. J. Electrochem., 2005, vol. 41, pp. 1282–1289.
Pan, B., Fang, X., and Tian, Y., Electrodeposition of Fe-diamond composite material for manufacture of diamond tools, Appl. Mech. Mater., 2010, vols. 37–38, pp. 398–401.
Zhou, P., Zhong, Y., Wang, H., Fan, L., Dong, L., Li, F., Long, Q., and Zheng, T., Behavior of Fe/nano-Si particles composite electrodeposition with a vertical electrode system in a static parallel magnetic field, Electrochim. Acta, 2013, vol. 111, pp. 126–135.
Gernon, M.D., Wu, M., Buszta, T., and Janney, P., Environmental benefits of methanesulfonic acid: comparative properties and advantages, Green Chem., 1999, vol. 1, pp. 127–140.
Finšgar, M. and Milošev, I., Corrosion behaviour of stainless steels in aqueous solutions of methanesulfonic acid, Corr. Sci., 2010, vol. 52, pp. 2430–2438.
Balaji, R. and Pushpavanam, M., Methanesulphonic acid in electroplating related metal finishing industries, Trans. Inst. Met. Finish., 2003, vol. 81, no. 5, pp. 154–158.
Martyak, N.M. and Seefeldt, R., Additive-effects during plating in acid tin methanesulfonate electrolytes, Electrochim. Acta, 2004, vol. 49, pp. 4303–4311.
Protsenko, V.S., Kityk, A.A., and Danilov, F.I., Kinetics and mechanism of chromium electrodeposition from methanesulfonate solutions of Cr(III) salts, Surf. Eng. Appl. Electrochem., 2014, vol. 50, no. 5, pp. 384–389.
Low, C.T.J. and Walsh, F.C., Electrodeposition of tin, copper and tin-copper alloys from a methanesulfonic acid electrolyte containing a perfluorinated cationic surfactant, Surf. Coat. Technol., 2008, vol. 202, pp. 1339–1349.
Danilov, F.I., Protsenko, V.S., Vasil’eva, E.A., and Kabat, O.S., Antifriction coatings of Pb-Sn-Cu alloy electro-deposited from methanesulphonate bath, Trans. Inst. Metal. Finish., 2011, vol. 89, no. 3, pp. 151–154.
Mohan, S., Vijayakumar, J., and Saravanan, G., Influence of CH3SO3H and AlCl3 in direct and pulse current electrodeposition of trivalent chromium, Surf. Eng., 2009, vol. 25, pp. 570–576.
Sidel’nikova, S.P., Petrov, Yu.N., and Gorodetskii, Yu.S., Investigation of the cathodic polarization and hydrogenation of deposits in the electrodeposition of iron from methylsulfate and sulfate electrolytes, Prot. Met., 1974, vol. 10, pp. 177–179.
Pleshka, E.D., Adhesion of iron coatings with steel and cast iron, Surf. Eng. Appl. Electrochem., 2008, vol. 44, no. 2, pp. 92–97.
Pleshka, E.D., Iron coatings from multicomponent methyl sulfate chloride electrolyte, Surf. Eng. Appl. Electrochem., 2008, vol. 44, no. 4, pp. 264–270.
Low, C.T.J., Wills, R.G.A., and Walsh, F.C., Electrodeposition of composite coatings containing nanoparticles in a metal deposit, Surf. Coat. Technol., 2006, vol. 201, pp. 371–383.
Wang, W., Hou, F.-Y., Wang, H., and Guo, H.-T., Fabrication and characterization of Ni-ZrO2 composite nanocoatings by pulse electrodeposition, Scripta Mater., 2005, vol. 53, pp. 613–618.
Huang, J.M., Li, Y., Zhang, G.F., Hou, X.D., and Deng, D.W., Electroplating of Ni-ZrO2 nanocomposite coatings on 40CrNiMo7 alloy, Surf. Eng., 2013, vol. 29, pp. 194–199.
Hou, F., Wang, W., and Guo, H., Effect of the dispersibility of ZrO2 nanoparticles in Ni-ZrO2 electroplated nanocomposite coatings on the mechanical properties of nanocomposite coatings, Appl. Surf. Sci., 2006, vol. 252, pp. 3812–3817.
Vasil’eva, E.A., Smenova, I.V., Protsenko, V.S., Konstantinova, T.E., and Danilov, F.I., Electrodeposition of hard iron-zirconia dioxide composite coatings from a methanesulfonate electrolyte, Russ. J. Appl. Chem., 2013, vol. 86, pp. 1735–1740.
Slipenyuk, A.M., Glinchuk, M.D., Bykov, I.P., Ragulya, A.V., Klimenko, V.P., Konstantinova, T.E., and Danilenko, I.A., ESR investigation of yttria stabilized zirconia powders with nanosize particles, Ferroelectrics, 2004, vol. 298, pp. 289–296.
Konstantinova, T.E., Ragulya, A.V., Doroshkevich, A.S., Volkova, G.K., and Glazunova, V.A., The mechanism of particle formation in Y-doped ZrO2, Int. J. Nanotechnol., 2006, vol. 3, pp. 29–38.
Yashchishyn, I.A., Korduban, A.M., Konstantinova, T.E., Danilenko, I.A., Volkova, G.K., Glazunova, V.A., and Kandyba, V.O., Structure and surface characterization of ZrO2-Y2O3-Cr2O3 system, Appl. Surf. Sci., 2010, vol. 256, pp. 7175–7177.
Zech, N. and Landolt, D., The influence of boric acid and sulfate ions on the hydrogen formation in Ni-Fe plating electrolytes, Electrochim. Acta, 2000, vol. 45, pp. 3461–3471.
Berçot, P., Peña-Muñoz, E., and Pagetti, J., Electrolytic composite Ni-PTFE coatings: An adaptation of Guglielmis model for the phenomena of incorporation, Surf. Coat. Technol., 2002, vol. 157, pp. 282–289.
Guglielmi, N., Kinetics of the deposition of inert particles from electrolytic baths, J. Electrochem. Soc., 1972, vol. 119, pp. 1009–1012.
Wang, S.-C. and Wei, W.-C., J., Kinetics of electroplating process of nanosized ceramic particle/Ni composite, Mater. Chem. Phys., 2003, vol. 78, pp. 574–580.
Bahadormanesh, B. and Dolati, A., The kinetics of Ni-Co/SiC composite coatings electrodeposition, J. Alloys Compd., 2010, vol. 504, pp. 514–518.
Erb, U., Size effects in electroformed nanomaterials, Key Eng. Mater., 2010, vol. 444, pp. 163–188.
Hall, E.O., The deformation and ageing of mild steel: III Discussion of results, Proc. Phys. Soc., Ser. B, 1951, vol. 64, pp. 747–753.
Petch, N.J., The upper yield stress of polycrystalline iron, Acta Met., 1964, vol. 12, pp. 59–65.
Khan, A.S., Zhang, H., and Takacs, L., Mechanical response and modeling of fully compacted nanocrystalline iron and copper, Int. J. Plast., 2000, vol. 16, pp. 1459–1476.
Mohajeri, S. and Dolati, A., Electrodeposition of Ni/WC nanocomposite in sulfate solution, Mater. Chem. Phys., 2011, vol. 129, pp. 746–750.
Aghaie, E., Najafi, A., Maleki-Ghaleh, H., and Mohebi, H., Effect of SiC concentration in electrolyte on Ni-SiC composite coating properties, Surf. Eng., 2013, vol. 29, pp. 177–182.
Gyftou, P., Pavlatou, E.A., and Spyrellis, N., Effect of pulse electrodeposition parameters on the properties of Ni/nano-SiC composites, Appl. Surf. Sci., 2008, vol. 254, pp. 5910–5916.
Mokabber, T., Rastegari, S., and Razavizadeh, H., Effect of electroplating parameters on properties of Zn-nano-TiO2 composite coatings, Surf. Eng., 2013, vol. 29, pp. 41–45.
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Protsenko, V.S., Vasil’eva, E.A., Smenova, I.V. et al. Electrodeposition of Fe and composite Fe/ZrO2 coatings from a methanesulfonate bath. Surf. Engin. Appl.Electrochem. 51, 65–75 (2015). https://doi.org/10.3103/S1068375515010123
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DOI: https://doi.org/10.3103/S1068375515010123