Skip to main content
Log in

Influence of activation on the pore structure of adsorbents obtained from coal–alkali mixtures

  • Chemistry
  • Published:
Coke and Chemistry Aims and scope Submit manuscript

Abstract

The activation of carbon sorbents in CO2 is investigated. The sorbents are produced by the thermolysis of naturally oxidized SS coal steeped in potassium hydroxide, with an alkali/coal ratio R KOH = 0.01 and 0.05 g/g. The influence of CO2 activation on the texture of the sorbents obtained is established. After 10-min activation, the increase in specific surface area of the sorbents is a maximum (about 100%). Longer activation increases the loss of material. The pore volume formed on activation is proportional to the proportion of carbon-bearing material removed. The volume of adsorbing pores formed in the sorbents is greatest when the loss of material is 25–35%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Butyrin, G.M., Vysokoporistye uglerodnye veshchestva (Highly Porous Carbon Materials), Moscow: Khimiya, 1976.

    Google Scholar 

  2. Mukhin, V.M. and Klushin, N.V., Proizvodstvo i primenenie uglerodnykh adsorbentov (Production and Application of Carbon Adsorbents), Moscow: Ross. Khim.- Tekhnol. Univ. im. D.I. Mendeleeva, 2012.

    Google Scholar 

  3. Manina, T.S., Fedorova, N.I., Semenova, S.A., and Ismagilov, Z.R., Processing low-grade oxidized coal to produce effective carbon sorbents, Coke Chem., 2012, vol. 55, no. 3, pp. 115–118.

    Article  Google Scholar 

  4. Manina, T.S., Fedorova, N.I., Semenova, S.A., and Ismagilov, Z.R., Porous structure of adsorbents based on naturally oxidized Kuznets Basin coal, Coke Chem., 2012, vol. 55, no. 11, pp. 429–431.

    Article  Google Scholar 

  5. Tamarkina, Yu.V., Kucherenko, V.A., and Shendrik, T.G., Development of the specific surface areas of natural coal in the course of thermolysis in the presence of potassium hydroxide, Russ. J. Appl. Chem., 2004, vol. 77, no. 9, pp. 1440–1443.

    Article  CAS  Google Scholar 

  6. Shendrik, T.G., Tamarkina, Y.V., Khabarova, T.V., Kucherenko, V.A., Chesnokov, N.V., and Kuznetsov, B.N., Formation of the pore structure of brown coal upon thermolysis with potassium hydroxide, Solid Fuel Chem., 2009, vol. 43, no. 5, pp. 309–313.

    Article  Google Scholar 

  7. Fenelonov, V.B., Vvedenie v fizicheskuyu khimiyu formirovaniya supramolekulyarnoi struktury adsorbentov i katalizatorov (Introduction into Physical Chemistry of Supramolecular Structure of Adsorbents and Catalysts), Novosibirsk: Sib. Otd., Ross. Akad. Nauk, 2002.

    Google Scholar 

  8. Tamarkina, Yu.V., Maslova, L.A., Khabarova, T.V., and Kucherenko, V.A., Adsorption properties of carbon materials produced by thermolysis of brown coal in the presence of alkali metal hydroxides, Russ. J. Appl. Chem., 2008, vol. 81, no. 7, pp. 1167–1170.

    Article  CAS  Google Scholar 

  9. Fedorova, N.I. and Semenova, S.A., Sorbents based on Mongolian coal, Coke Chem., 2012, vol. 55, no. 4, pp. 146–149.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to T. S. Nechaeva.

Additional information

Original Russian Text © T.S. Nechaeva, N.I. Fedorova, Z.R. Ismagilov, 2017, published in Koks i Khimiya, 2017, No. 6, pp. 25–29.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nechaeva, T.S., Fedorova, N.I. & Ismagilov, Z.R. Influence of activation on the pore structure of adsorbents obtained from coal–alkali mixtures. Coke Chem. 60, 239–242 (2017). https://doi.org/10.3103/S1068364X17060072

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068364X17060072

Keywords

Navigation