Skip to main content
Log in

Production of a mesoporous carbon adsorbent from carbon black and petroleum pitch by high-temperature roasting and steam activation

  • Chemistry
  • Published:
Coke and Chemistry Aims and scope Submit manuscript

Abstract

Mesoporous carbon adsorbent may be produced from carbon black and petroleum pitch by high-temperature roasting (at 1100°C) and subsequent steam activation. The samples obtained are compared with samples roasted at 700°C, with losses of 5–70 wt %. It is found that raising the roasting temperature increases the mesopore surface by a factor of 1.5–2.5 (to 200–300 m2/g) and reduces the micropore volume by a factor of 1.5–3.0. The adsorbent obtained may be effectively used in extracting materials from solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Kienle, H. and Bader, E., Aktivkohle und ihre Industrielle Anwendung, Stuttgart: Ferdinand Enke-Verlag, 1980.

    Google Scholar 

  2. Lorenc-Grabowska, E. and Gryglewicz, G., Adsorption characteristics of Congo Red on coal-based mesoporous activated carbon, Dyes Pigm., 2007, vol. 74, no. 1, pp. 34–40.

    Article  CAS  Google Scholar 

  3. Tamai, H., Kakii, T., Hirota, Y., et al., Synthesis of extremely large mesoporous activated carbon and its unique adsorption for giant molecules, Chem. Mater., 1996, vol. 8, no. 2, pp. 454–462.

    Article  CAS  Google Scholar 

  4. Surovikin, V.F., Surovikin, Yu.V., and Tsekhanovich, M.S., New fields in the technology for manufacturing carbon-carbon materials. Application of carbon-carbon materials, Russ. J. Gen. Chem., 2007, vol. 77, no. 12, pp. 2301–2310.

    Article  CAS  Google Scholar 

  5. Kugatov, P.V. and Zhirnov, B.S., Porous carbon/carbon composites produced from carbon black and petroleum pitch, J. Porous Mater., 2013, vol. 20, no. 4, pp. 875–882.

    Article  CAS  Google Scholar 

  6. Kugatov, P.V., Bashirov, I.I., and Zhirnov, B.S., Synthesis of low-ash granules from carbon black and petroleum pitch by steam activation, Neftegaz. Delo, 2015, no. 2, pp. 281–306.

    Google Scholar 

  7. GOST (State Standard) 7885–86: Carbon Black for Rubber Industry. Specifications, Moscow: Izd. Standartov, 1988.

  8. Rubinshtein, A.M. and Klyachko-Gurvich, A.L., Simple and rapid methods for determination of the surface area of catalysts, Kinet. Katal., 1962, vol. 3, no. 4, pp. 599–601.

    Google Scholar 

  9. Kiselev, A.V., Iogansen, A.V., Sakodynskii, K.I., et al., Fiziko-khimicheskoe primenenie gazovoi khromatografii (Physical-Chemical Implementation of Gas Chromatography), Moscow: Khimiya, 1973.

    Google Scholar 

  10. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, New York: Academic, 1991.

    Google Scholar 

  11. Isirikyan, A.A. and Kiselev, A.V., The absolute adsorption isotherms of vapors of nitrogen, benzene and nhexane, and the heats of adsorption of benzene and nhexane on graphitized carbon blacks. I. Graphitized thermal blacks, J. Phys. Chem., 1961, vol. 65, no. 4, pp. 601–607.

    CAS  Google Scholar 

  12. GOST (State Standard) 17219–71: Active Carbons. Method for Determination of Summary Pore Volume by the Moisture Capacity Test, Moscow: Izd. Standartov, 1973.

  13. Zhirnov, B.S., Kineticheskie issledovaniya i modelirovanie promyshlennykh khimiko-tekhnologicheskikh protsessov s uchastiem ugleroda (Kinetic Studies and Modeling of Industrial Chemical Technological Processes Using Carbon), Ufa: Inst. Neftekhimpererabotki, 2010.

    Google Scholar 

  14. Orlov, V.Yu., Komarov, A.M., and Lyapina, L.A., Proizvodstvo i ispol’zovanie tekhnicheskogo ugleroda dlya rezin (Production and Use of Technical Carbon for Rubbers), Yaroslavl: Izd. Aleksandra Rutman, 2002.

    Google Scholar 

  15. Syunyaev, Z.I., Proizvodstvo, oblagorazhivanie i primenenie neftyanogo koksa (Production, Refining, and Implementation of Petroleum Coke), Moscow: Khimiya, 1973.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. V. Kugatov.

Additional information

Original Russian Text © P.V. Kugatov, I.I. Bashirov, B.S. Zhirnov, 2016, published in Koks i Khimiya, 2016, No. 9, pp. 31–34.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kugatov, P.V., Bashirov, I.I. & Zhirnov, B.S. Production of a mesoporous carbon adsorbent from carbon black and petroleum pitch by high-temperature roasting and steam activation. Coke Chem. 59, 345–348 (2016). https://doi.org/10.3103/S1068364X16090052

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068364X16090052

Keywords

Navigation