Abstract
Corrosion tests of SCh15 cast iron, St.3, and St.3 with an aluminized coating are performed in certain compositions of salt melts of 10% MgCl2–KCl–NaCl and 10% MgCl2–KCl–NaCl–CaCl2 systems with concentrations of 10, 25, and 40% CaCl2, as well as in the 10% MgCl2–45% KCl–20% NaCl–25% NaBr melt and in a gas phase over these melts at 700°C. Corrosion rates of metallic samples are found by a gravimetric method. Concentrations of impurities of halogenides and hydrogen halogenides in air blown through a reactor with melts and samples are determined by the chemical analysis of absorption solutions. It is shown that the aluminizing of carbon steel can decrease the corrosion rate in a gas phase over a salt melt by a factor of 5–70. The mechanism of formation of gases aggressive with respect to carbon steel and cast iron in atmospheric air contacting with the salt chloride melt is considered. The acceleration of the formation of hydrogen chrloride and chlorine during the interaction of the salt melt with atmospheric air under the effect of corrosion products of iron is revealed.
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REFERENCES
Moskvitin, V.I., Nikolaev, I.V., and Fomin, B.A., Metallurgiya legkikh metallov (Metallurgy of Light Metals), Moscow: Intermet Inzhiniring, 2005.
D’yachenko, A.N., Kraidenko, R.I., and Kurchenko, E.I., Corrosion resistance of metals and alloys in the fluoride system, Vestn. Perm. Nats. Issled. Polytekh. Univ. Ser. Mashinostr., 2017, vol. 19, no. 4. https://doi.org/10.15593/2224-9877/2017.4.05
Barabanov, V.G., Zotikov, V.S., Limonova, L.P., Maksimov, B.N., Semerikova, A.I., and Stepanov, V.P., Korroziya oborudovaniya v proizvodstve galogensoderzhashchikh veshchestv: Spravochnoe izdanie (Corrosion of Equipment in the Production of Halogen-Containing Substances: Reference Book), Zotikov, V.S, Ed., St. Petersburg: TEZA, 1998.
Reznikov, I.L., Tanaev, A.F., and Ukshe, N.S., Corrosion of cast iron, carbon steel, and chromium–nickel steels at 400–600°C in air containing HCl, Cl2, H2O, and SO2, Zashch. Met., 1972, vol. 8, no. 2, pp. 157–162.
Putina, O.A., Investigation into the nickel and steel corrosion in molten chlorides of alkaline and alkali-earth metals and in liquid magnesium, Cand. Sci. (Chem) Dissertation, Sverdlovsk: UPI, 1973.
Barannik, I.A., Komelin, I.M., Sikorskaya, I.L., and Zhurov, V.V., RF Patent 41575, 2009.
Nikolaev, M.M., Yazev, V.D., Kashkarov, I.A., Rymkevich, D.A., and Chutkov, A.P., RF Patent 2283886, 2006.
Gribov, V.I., Mikhailov, A.O., and Ryaposov, Yu.A., RF Patent 2400685, 2010.
Gilad Golub, Katsnelson Gennary, Zinn Menachem, and Aghion Eliyahu, US Patent 6132490, 2000.
Komelin, I.M., Barannik, I.A., Petriv, M.I., and Zhurov, V.V., RF Patent 36141 1999.
Barannik, I.A., Komelin, I.M., Gerb, A.P., and Petriv, M.I., RF Patent 12704, 2005.
Putina, O.A., Putin, A.A., Gulyakin, A.I., Nechaev, N.P., Rubel’, O.A., Lyamin, S.G., Novikov, S.M., Zhulanov, N.K., Belkin, N.A., Temnikov, V.V., and Remeslov, M.N., RF Patent 2217512, 2002.
Teterin, V.V., Bezdolya, I.N., Shundikov, N.A., Mikhailov, E.F., and Paderina, N.S., RF Patent 2407813, 2009.
Kochergin, V.P., High-temperature corrosion of transition metals in ionic melts, Soros. Obraz. Zh., 1997, no. 8, pp. 60–65.
Kochergin, V.P., Putina, O.A., Devyatkin, V.N., and Kanaeva, E.T., Revisiting steady-state potential of steel St.3 in molten chlorides of sodium, potassium, and alkali-earth metals, Tr. VAMI, 1971, no. 75, pp. 51–55.
Kochergin, V.P. and Stolyarova, G.I., Dissolution of iron in molten mixtures of chlorides of lithium and potassium, sodium and potassium, Zh. Prikl. Khim., 1956, no. 5, pp. 730–733.
Smirnov, M.V., Krasil’nikova, N.A., and Ozeryanaya, I.N., Interaction of iron with pure chlorides of alkali metals and solutions of hydrogen chloride in them, Tr. Inst. Elektrokhim. UNTs AN SSSR, 1970, no. 16, pp. 78–81.
Lukmanova, G.L. and Vil’nyanskii, Ya.E., Solubility of certain gases in the melt of metal chlorides, Izv. Vyssh. Uchebn. Zaved. Khim. Khim. Tekhnol., 1966, vol. 9, no. 4, pp. 537–540.
Ozeryanaya, I.N., Tkhai, V., and Smirnov, M.V., Solubility of hydrogen chloride in molten magnesium and strontium chlorides, in collected articles: Elektrokhimiya rasplavlennykh solevykh i tverdykh elektrolitov (Electrochemistry of molten salt and solid electrolytes), Tr. Inst. Elektrokhim. UNTs AN SSSR, 1973, no. 19, pp. 13–16.
Nekrasov, V.N., Fizicheskaya khimiya rastvorov galogenov v galogenidnykh rasplavakh (Physical Chemistry of Halogen Solutions in Halide Melts), Moscow: Nauka, 1992.
Novozhilov, A.L., Thermodynamics and structure of solutions of gases and water vapors in molten salts, Extended Abstract of Doctoral (Chem.) Dissertation, Stavropol’: Inst. Elektrokhim. UNTs AN SSSR, 1986.
Novozhilov, A.L., Gribova, E.I., and Devyatkin, V.N., Investigation into the state of HCl in molten chlorides of alkaline and alkali-earth metals by the IR spectroscopy method, Zh. Neorg. Khim., 1972, vol. 17, no. 8, pp. 2078–2080.
Novozhilov, A.L., Solubility of hydrogen chloride in the melts of the KCl–MgCl2 system, Zh. Neorg. Khim., 1984, vol. 29, no. 1, pp. 218–221.
Novozhilov, A.L, Gribova, E.I., and Devyatkin, V.N., Solubility of hydrogen chloride in molten chlorides of alkali-earth metals, Zh. Neorg. Khim., 1972, vol. 17, no. 9, pp. 2570–2572.
Putina, O.A., Bondarev, S.N., Vyatkin, I.P., Kanaev, I.E., and Brandman, O.I., Corrosion resistance of metal structures of the continuous magnesium refining furnace, in collected articles: Proizvodstvo magniya i titana (Production of Titanium and Magnesium), Tr. VAMI, 1972, no. 883, pp. 64–68.
Strelets, Kh.L. and Desyatnikov, O.G., Density of molten salts of the isoconcentration section (10 wt % MgCl2) of the MgCl2–CaCl2–NaCl–KCl system, Tr. VAMI, 1957, no. 39, pp. 401–412.
Tomashov, N.D., Zhuk, N.P., Titov, V.A., and Vedeneeva, M.A., Laboratornye raboty po korrozii i zashchite metallov (Laboratory Works on Corrosion and Protection of Metals), Moscow: Metallurgiya, 1971.
Zabyelin, I.V., Komelin, I.M., Barannik, I.A., and Sikorskaya, I.L., On specific features of operating crucibleless salt-bath furnaces, in: Magnesium—Science, Technology, and Applications, Mater. Sci. Forum, 2005, vol. 488–489, pp. 89–94. doi 10.4028/www.scientific.net/MSF.488-489.89.
Furman, A.A., Neorganicheskie khloridy (Inorganic Chlorides), Moscow: Khimiya, 1980.
Pechkovskii, V.V., Aleksandrovich, Kh.M., and Pinaev, G.F., Tekhnologiya kaliinykh udobrenii (Technology of Potassium Fertilizers), Minsk: Vysheishaya Shkola, 1968.
Loginov, N.A. and Oleinikova, V.A., Equilibrium concentration of Fe3+ in NaCl, (NaCl–KCl), KCl, and CsCl melts in equilibrium with iron, Rasplavy, 2000, no. 6, pp. 27–30.
Pechkovskii, V.V. and Vorob’ev, N.I., Thermochemical transformations of iron chlorides, Zh. Neorg. Khim., 1964, vol. IX, no. 1, pp. 12–19.
Latina, Z.I. and Furman, A.A., Interaction of iron chloride with iron oxide, Zh. Prikl. Khim., 1970, no. 4, pp. 830–834.
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Komelin, I.M., Lysenko, A.P. & Kondrateva, D.S. Corrosion of Carbon Steel and Cast Iron in a Gas Phase over Salt Melts Used in the Magnesium Industry. Russ. J. Non-ferrous Metals 60, 125–138 (2019). https://doi.org/10.3103/S1067821219020056
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DOI: https://doi.org/10.3103/S1067821219020056