Abstract
Low-basic Cybber anionites with various functional groups and a matrix type are tested for the recovery of rhenium from multicomponent sulfuric acid solutions. It is established that anionite SX002 manifests an increased capacity during the sorption from solutions with a low Re content, while anionite ALX220 is applicable to recover Re at its high concentrations in the solution. The ionic background of the industrial solution affects the capacity of sorbents with respect to rhenium. When studying the kinetic characteristics, it is revealed that sorption processes on ionites are limited by the internal diffusion. The tests of ionites as applied to Cr-containing solutions indicate the possibility of using anionites ALX220 and SX002 to recover rhenium.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Palant, A.A., Troshkina, I.D., and Chekmarev, A.M., Metallurgiya reniya (Metallurgy of Rhenium), Moscow: Nauka, 2007.
Balmasov, G.F., Blokhin, A.A., and Kopyrin, A.A., Recovery of rhenium in the course of copper–nickel concentrates, Tsvetn. Met., 1995, no. 1, pp. 32–34.
Paretskii, V.M., Besser, A.D., and Gedgagov, E.I., Ways to increase the production of rhenium from ore and anthropogenic feedstock, Tsvetn. Met., 2008, no. 10, pp. 17–21.
Khalezov, A.B., The question of broadening the mineral feedstock base of rhenium in the Russian Federation, Razved. Okhr. Nedr, 2009, pp. 13–17.
Sadykanova, S.E., Zagorodnyaya, A.N., and Abisheva, Z.S., Behavior of rhenium in the course of extraction processing of washing sulfuric acid with the formation of ammonium perrhenate, Trudy Mezhdunarodnoi konferentsii “Metallurgiya XXI veka—sostoyanie i strategiya razvitiya (Proc. Int. Conf. “Metallurgy of 21st Century—The State and Developmental Strategy”), Almaty, 2006, pp. 311–314.
Kasikov, A.G., Areshina, N.S., Kudryakov, M.V., and Khomchenko, O.A., Complex processing of washing sulfuric acid of copper–nickel production by electroextraction method, Khim. Tekhnol., 2004, no. 6, pp. 25–31.
Ospanov, E.A., Gedgagov, E.I., Ospanov, N.A., and Zakhar’yan, S.V., Development of production technology of high-purity ammonium perrhenate at the Balkhash copper-smelting plant of Republic Kazakhstan, Abstracts of Papers, 7-oi Mezhdunarodnyi simpozium “Tekhnetsii i renii: izuchenie svoistv i primenenie” (7th Int. Symp. “Technetium and Rhenium: Investigation into the Properties and Application”), Moscow, 2011, p. 75.
Petrov, G.V., Boduen, A.Ya., Spynu, A.Yu., and Boginskaya, A.S., Behavioristic peculiarities of rare microcomponents in the course of processing copper ores and ways to increase their production, in Sbornik dokladov 4-go Mezhdunarodnogo kongressa “Tsvetnye metally–2012” (Proc. 4th Int. Congr. “Nonferrous Metals–2012”), Krasnoyarsk, 2012, pp. 158–160.
Abisheva, Z.S., An increase in the degree of recovery of rhenium at the Zhezkazgan Copper Smeltery, Tsvetn. Met., 2003, no. 6, pp. 69–73.
Zagorodnyaya, A.N., Abisheva, Z.S., and Bukurov, T.N., Distribution of rhenium and osmium by processing products of sulfide copper feedstock, Tsvetn. Met., 1997, no. 9, pp. 47–50.
Zagorodnyaya, A.N., Composition of precipitates in the course of solid-phase reextraction rhenium, in Kompleksnaya pererabotka mineral’nogo syr’ya: Sbornik trudov (Complex Processing of Mineral Feedstock: Collected Works), Almaty, 2002, pp. 52–56.
Blokhin, A.A., Amosov, A.A., and Murashkin, Yu.V., Evaluation of possibility of sorption recovery of rhenium from washing sulfuric acid of wet purification systems of copper–nickel production, Tsvetn. Met., 2006, no. 8, pp. 94–98.
Boduen, A.Ya., Petrov, G.V., Spynu, A.Yu., et al., Secondary recovery of rare microelements in the course of complex processing of sulfide copper ores, Metallurg, 2014, no. 1, pp. 83–85.
Description of Cybber Anionites. http:// www.szhk.ru/osnovnye-smoly-dlya-gidrometallurgii.
Ionity v tsvetnoi metallurgii (Ionites in Nonferrous Metallurgy) Lebedev, K.B., Ed., Moscow: Metallurgiya, 1975.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © G.V. Petrov, A.Ya. Boduen, S.B. Fokina, M.S. Sidorova, 2015, published in Izvestiya VUZ. Tsvetnaya Metallurgiya, 2015, No. 4, pp. 9–14.
About this article
Cite this article
Petrov, G.V., Boduen, A.Y., Fokina, S.B. et al. Sorption recovery of rhenium from chromium-containing sulfate solutions by cybber low-basic anionites. Russ. J. Non-ferrous Metals 56, 500–504 (2015). https://doi.org/10.3103/S1067821215050120
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1067821215050120