Abstract
Special features of the formation of the defect and impurity states of diamond single crystals grown in the Fe–Mg–Al–C growth system by the temperature gradient method at the pressure 7.2–8.2 GPa and temperature 1700–1900°C have been investigated. It has been shown that as the magnesium content of the growth system increases, the type of the grown crystals changes in the following sequence: IIa → IIb.
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Novikov, N.V. and Shulzhenko, A.A., The increase of synthetic diamond growth, in Science and Technology of New Diamond, Saito, S. and Yoshikava, M., Eds., Tokio: KTK Scientific Publishers, Terra Scientific Publishers Co, 1990, pp. 217–219.
Kovalenko, T.V. and Ivakhnenko, S.A., Properties of Diamonds Seed-Grown in the Magnesium–Carbon System, J. Superhard Mater., 2013, vol. 35, no. 3, pp. 131–136.
Strong, N.M. and Wentorf, R.N., The growth of large diamond crystals, J. Naturwissenschften, 1972, vol. 59, no. 1, pp. 1–7.
Wentorf, R.H., Some studies of diamond growth rates, J. Phys. Chem., 1971, vol. 75, no. 12, pp. 1833–1837.
Lysakovskii, V.V., Regularities of the diamond crystallization onto a seed in the Fe–Co–Ti (Zr)–C solution–melt systems, Cand. Sci. (Eng.) Dissertation, Kiev, 2008.
Suprun, E.M., Kalenchuk, V.A., Ivakhnenko, S.A., et al., Defect-and-impurity state of type Ib diamond single crystals of a cubic habit, J. Superhard Mater., 2016, vol. 38, no. 6, pp. 377–381.
Sinteticheskie sverkhtverdye materialy (Synthetic superhard materials), 3 vols, vol. 1, Synthesis of superhard materials, Novikov, N.V., Ed., Kiev: Naukova Dumka, 1986.
Collins, A.T. and Williams, A.W.S., The nature of the acceptor centre in semiconducting diamond, J. Phys. C: Solid St. Phys., 1971, vol. 4, pp. 1789–1800.
Fisher, D., Sibley, S.J., and Kelly, C.J., Brown color in natural diamond and interaction between the brown related and other color-inducing defects, J. Phys.: Condensed Matter., 2009, vol. 21, no. 36, pp. 1–10.
Novikov, N.V., Kocherzhinsky, Yu.A, Shul’man, L.A., et al., Fizicheskie svoistva almazov. Spravochnik, (Physical properties of diamonds. Handbook), Novikov, N.V., Ed., Kiev: Naukova Dumka, 1987.
Kanda, H., Akaishi, M., and Yamaoka, S., Synthesis of diamond with the highest nitrogen concentration, Diamond Relat. Mater., 1999, vol. 8, nos. 8–9, pp. 1441–1443.
Huang, G.-F., Zheng, Y.-J., Li, Z.-C., et al., Effects of Mg on diamond growth and properties in Fe–C system under high pressure and high temperature conditions, Chin. Phys. B, 2016, vol. 25, no. 8, art. 088104.
Kovalenko, T.V., Ivakhnenko, S.A., and Kutsai, A.M., Special features of the defect-and-impurity state of diamond produced in the magnesium–carbon system, Eastern-European J. Enterprise Technologies, 2015, vol. 3, no. 11 (75), pp. 39–42.
Kovalenko, T.V., Ivakhnenko, S.A., Belyavina, N.N., et al., Phase transformations in the Fe-Mg–C system at high pressures, in Porodorazrushayushchii i metalloobrabatyvayushchii instrument—tekhnika i technologiya ego izgotovleniya i primeneniya (Rock destruction and metal-working tools—techniques and technology of the tool production and applications), Collect. Papers, Kiev: Bakul’ ISM, Nat. Ac. Sci. Ukraine, 2016, issue 19, pp. 327–334.
Kovalenko, T.V., Romanko, L.A., and Ivakhnenko, S.A., Electro-physical properties of semiconductor diamonds grown in the magnesium–carbon system, Int. Conf. on Materials and coatings under extreme conditions (MEE-2016): Collect. Papers, Kiev: 2016, p. 58.
Lysakovskii, V.V., Special features of growing diamond single crystals in the Fe–Co–Zr–C system, J. Superhard Mater., 2014, vol. 36, no. 5, pp. 303–307.
Lysakovskii, V.V. and Ivakhnenko, S.A., Kinetics of diamond single crystals growth in Fe–Co solvents doped with titanium and zirconium, Ibid., 2009, vol. 31, no. 1, pp. 7–11.
Khokhryakov, A.F., Sokol, A.G., Borzdov, Y.M., et al., Morphology of diamond crystals grown in magnesium-based systems at high temperatures and high pressures, J. Crystal Growth, 2015, vol. 426, no. 15, pp. 276–282.
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Original Russian Text © T.V. Kovalenko, S.A. Ivakhnenko, V.V. Lysakovsky, S.A. Gordeev, A.V. Burchenya, 2017, published in Sverkhtverdye Materialy, 2017, Vol. 39, No. 2, pp. 14–19.
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Kovalenko, T.V., Ivakhnenko, S.A., Lysakovsky, V.V. et al. Defect-and-impurity state of diamond single crystals grown in the Fe–Mg–Al–C system. J. Superhard Mater. 39, 83–87 (2017). https://doi.org/10.3103/S1063457617020022
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DOI: https://doi.org/10.3103/S1063457617020022