Skip to main content
Log in

Increasing the wear resistance of the T15K6 hard alloy by boriding and complex saturation with boron and copper

  • Production, Structure, Properties
  • Published:
Journal of Superhard Materials Aims and scope Submit manuscript

Abstract

The formation of complex diffusion boride layers on the T15K6 hard alloy using the powder method has been studied. The phase and chemical compositions, thickness, and microhardness of the layers produced on the hard alloy have been defined. It has been found that the diffusion layers, produced in a borating medium with an addition of copper-containing compounds, which act as the copper source, consist of the TiB, CoB, WC, and Cu phases. The boriding makes it possible to form boride phases in a surface zone of the hard alloy with a microhardness up to 33 GPa, and complex saturation with boron and copper to 25 GPa as compared with the basic material (13.5 GPa) and thus, the wear resistance of the T15K6 hard alloy is increased by a factor of 2.0–2.2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tretyakov, V.I., Metallokeramicheskie tverdye splavy (Metal-ceramic alloys), Moscow: Metallurgizdat, 1962.

    Google Scholar 

  2. Bondarenko, V.P., Matveichuk, A.A., and Baranovskii, A.M., Unique hard alloy products and tools, Instrumental’nyi Svit, 2004, no. 2, pp. 6–8.

    Google Scholar 

  3. Bondarenko, V.P., Baranovskii, A.M., and Aronin, I.Ya., The potentiality of Alkon-Tverdosplav for production of drilling and stone-working tools, in Burovoi i kamneobrabatyvayushchii instrument—tekhnika i tekhnologiya ego izgotovleniya i primeneniya (Drilling and Stone-working Tools—Techniques and Technology of the Tool Production and Applications), Mater. 2nd Int. Conf., Morskoe, Crimea, Sept. 6–11, 1999. Kiev: ISM, NAS of Ukraine, 1999, pp. 42–43.

    Google Scholar 

  4. Bondarenko, V.P., Baranovskii, A.M., and Sotnikova, L.L., Novel hard alloys and fields of their applications, Instrumental’nyi Svit, 2004, no. 1(21), pp. 28–29.

    Google Scholar 

  5. Bondarenko, V.P., Botvinko, V.P., and Moshkun, V.F., Effect of microadditives of Cr3C2 and VC chromium and vanadium carbides on the properties of WC–6CoR for matrices of high-pressure apparatuses, in Porodorazrushayushchii i metalloobrabatyvayushchii instrument—tekhnika i tekhnologiya ego izgotovleniya i primeneniya (Rock Destruction and Metal-Working Tools—Techniques and Technology of the Tool Production and Applications), Collect. Sci. Papers, Kiev: Bakul’ ISM, Nat. Acad. Sci. Ukraine, 2004, issue 7, pp. 249–251.

    Google Scholar 

  6. Bondarenko, V.P., Andreiev, I.V., Martuniva, L.M., and Epik, I.V., Patent of Ukraine 75190, 15.05.2006, Byul. no. 3.

  7. Bondarenko, V.P. and Pavlotskaya, E.G., Spekanie vol’framovykh tverdykh splavov v pretsizionno-kontroliruemoi gazovoi srede (Sintering of tungsten hard alloys in precision-controlled gas medium), Kiev: Naukova Dumka, 1995.

    Google Scholar 

  8. Marinenko, S., Bodrova, L, Prokopiv, M., et al., Effect of the thermal-compression treatment on the microstructure and mechanical properties of hard alloys based on TiC–(VC, NbC, WC), Visnuk of Pulyui Ternopil’ State University, 2008, vol. 13, no. 4, pp. 40–48.

    Google Scholar 

  9. Prokopiv, N.M., Bondarenko, V.P., Kharchenko, O.V., and Melniichuk, Iu.A., Determination of the stability of WC–10Co fine-grained hard alloy at a cyclic impact turning of steel, Rezanie i Instrument v Technologicheskikh Sistemakh, 2012, issue 82, pp. 224–235.

    Google Scholar 

  10. Berzina, I.G., Gusev, E.B., Zakharov, B.V., Fedina, G. N., and Fedin, V. M., Distribution of boron, tungsten, titanium, and cobalt in borated hard alloys, Physics of Metals and Metal Science, 1984, vol. 57, issue 4, pp. 713–718.

    CAS  Google Scholar 

  11. Zakhariev, Z., Petrov, K., and Christov, M., Preparation and some properties of boride diffusion layers hard WC–TiC–Co alloys, J. Less-Common Metals, 1981, vol. 82, pp. 57–62.

    Article  CAS  Google Scholar 

  12. Berzina, I.G., Gusev, E.B., Zakharov, B.V., et al., On the boron distribution in a diffuse zone of borides hard alloys used to manufacture and machine of parts of a rolling stock, Papers of the Institute of Rail Transport Engineers, MIET, 1982, issue 701, pp. 24–27.

    Google Scholar 

  13. Chernega, S.M., Poliakov, I.A., and Krasovskiy, M.A., Complex saturation of a carbon steel with boron and copper, Scientific Records: Collection of notes of Institutes (Lutsk Nat. Techn. University), 2015, issue 49, pp. 165–171.

    Google Scholar 

  14. Pokhmursky, V.I., Dalisov, V.B., and Golubets, V.M., Povyshenie dolgovechnosti detalei mashin s pomoshch’yu diffusionnykh pokrytii (Increasing the durability of machine elements with the use of diffusion coating), Kiev: Naukova Dumka, 1980.

    Google Scholar 

  15. Balandin, Yu.A., Complex saturation of tool steels surfaces with boron, copper, chromium in a fluidizated layer, Proc. of universities. Ferrous metallurgy, 2005, no. 5.

  16. Svoistva elementov: Spravochnik V 2 chastyakh. Ch. 1, Fizicheskie svoistva (Properties of elements: Reference book, in 2 parts, Part 1, Physical properties, Samsonov, G.V., Ed., Moscow: Metallurgy, 1976.

  17. Diagrammy sostoyaniya dvoinykh metallicheskikh system: Sprav., (Phase diagrams of binary metal systems: Reference book), in 3 vol., vol. 2, Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1997.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. M. Chernega.

Additional information

Original Ukrainian Text © S.M. Chernega, I.A. Poliakov, M.A. Krasovskiy, 2016, published in Sverkhtverdye Materialy, 2016, Vol. 38, No. 3, pp. 54–62.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chernega, S.M., Poliakov, I.A. & Krasovskiy, M.A. Increasing the wear resistance of the T15K6 hard alloy by boriding and complex saturation with boron and copper. J. Superhard Mater. 38, 190–196 (2016). https://doi.org/10.3103/S1063457616030060

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1063457616030060

Keywords

Navigation