Abstract
A sorbent based on Zn/Al-hydrotalcite intercalated by hexacyanoferrate (II)-ions is proposed for 137Cs concentration and its further radiometric determination in natural waters. Parameters for the optimal sorptive extraction of radiocesium from waters under static conditions and direct radiometric measurements have been determined. The use of ferrocyanide sorbent is shown to provide a good potential in analytical schemes of 137Cs concentration from waters with high salt background.
Similar content being viewed by others
References
Radioaktivnye veshchestva. Vrednye veshchestva. Gigienicheskie normativy (Radioactive Substances. Harmful Substances. Hygienic Regulations), Moskvin, A.V., ed., St. Petersburg: ANO NPO Professional, 2004.
Demchuk, V.V., Martyniuk, O.V., Fedorenko, O.V., et al., Dovkillia ta zdorovia, 2010, no. 2, pp. 50–57.
Belyaev, I.K., Zhorova, E.S., Kalistratova, V.S., et al., Med. radiologiya i radiats. bezopasnost’, 2012, vol. 57, no. 4, pp. 62–70.
DSTU 7525:2014. Voda pytna. Vymogy ta metody kontroliuvannia yakosti (Standard DSTU 7525:2014. Potable Water. Requirements and methods of Quality Control), Introd. on February 1, 2015.
DSanPiN 2.2.4-171-10. Gigienichni vymogy do vody pytnoi, pryznachenoi dlia spozhyvannia liudynoiu (State sanitary rules and norms (DSanPiN 2.2.4-171-10). Hygienic Requirements to the Potable Water Intended for Human Use), Ofits. visn. Ukrainy, 2010, no. 51, pp. 100–129.
Gillyarovich, E.L., Gryaznov, A.N., Inikhov, A.G., et al., Sovremennaya praktika obespecheniya kachestva izmerenii ioniziruyushchikh izluchenii. Yadernye izmeritel’no-informatsionnye tekhnologii (Up-to-date Practice of Ensuring the Quality of Measurements of Ionizing Radiations. Nuclear Instrumentation-and-Information Technologies), Moscow: NITs CNIIP, 1997.
Plyushchev, V.E. and Stepin, B.D., Analiticheskaya khimiya rubidiya i tseziya (Analytical Chemistry of Rubidium and Cesium), Moscow: Nauka, 1975.
Azimov, A.N., Hushmuradov, S.K., Muminov, I.T., et al., Radiat. Meas., 2008, vol. 43, pp. 66–71.
Jenkins, J.H., Fischbach, E., Javorsek, D., et al., Appl. Radiat. Isot., 2013, vol. 74, pp. 50–55.
Nesterov, S.V., Uspekhi Khimii, 2000, vol. 69, no. 9, pp. 840–855.
Yakshin, V.V., Vilkova, O.M., Tananaev, I.G., et al., Dokl. AN Rossii, 2008, vol. 422, no. 5, pp. 641–644.
Ivanets, D.V., Safiulina, A.M., Kudryavtsev, E.M., et al., Vest. MGU, Ser. Khimiya, 2012, vol. 53, no. 4, pp. 269–271.
Raut D.R., Mohapatra, P.K., Choudhary, M.K., et al., J. Membrane Sci., 2013, vol. 429, pp. 197–205.
Abramov, A.A. and Fedoseev, V.M., Ros. khim. zhurn., 2005, vol. 49, no. 2, pp. 102–106.
Shelkovnikova, L.A., Kargov, S.I., Gavlina, O.T., et al., Zhurn. fiz. khimii, 2013, vol. 87, no. 1, pp. 112–116.
Pratt, L.M., Szostak, R., Khan, I.M., et al., J. Macromol. Sci., 1997, vol. 34, no. 2, pp. 281–289.
Metodicheskie rekomendatsii po sanitarnomu kontrolyu za soderzhaniem radioaktivnykh veshchestv v ob”ektakh vneshnei sredy (Guidelines for Sanitary Control over the Content of Radioactive Substances in Objects of External Environment), Marei, A.N. and Zykova, A.S., eds., Moscow: Minzdrav, 1980.
Tananaev, I.V., Seifer, G.B., Kharitonov, Yu.Ya., et al., Khimiya Ferrotsianidov (Chemistry of Ferrocyanides), Moscow: Nauka, 1971.
Tarkovskaya, I.A., Antonova, L.S., Goba, V.E., et al., Zhurn. Prikl. Khimii, 1995, vol. 68, no. 4, pp. 624–629.
Myasoedova, G.V. and Nikashina, V.A., Ros. Khim. Zhurn., 2006, vol. 50, no. 5, pp. 55–63.
Liao, S., Xue, Ch., Wang, Y., et al., Sep. Purif. Technol., 2015, vol. 139, pp. 63–69.
Chen, R., Tanaka, H., Kawamoto, T., et al., Electrochim. Acta, 2013, vol. 87, pp. 119–125.
Mahmoud, M.R. and Seliman, A.F., Appl. Radiat. Isot., 2014, vol. 91, pp. 141–154.
Zhang, H., Zhao, X., Wei, J., et al., Nucl. Eng. Des., 2014, vol. 275, pp. 322–328.
Avramenko, V., Bratskaya, S., Zheleznov, V., et al., J. Hazard. Materials, 2011, vol. 186, no. 2/3, pp. 1343–1350.
Remez, V.P., Zelenin, V.I., Smirnov, A.L., et al., Sorbts. Khromat. Protsessy, 2009, vol. 9, no. 6, pp. 783–788.
Pshinko, G.N., Puzyrnaya, L.N., Kobets, S.A., et al., Radiokhimiya, 2015, vol. 57, no. 3, pp. 221–226.
Pshinko, G.N., Kosorukov, A.A., Puzyrnaya, L.N., and Kobets, S.A., Radiochem., 2013, vol. 55, no. 6, pp. 601–604.
Kosorukov, A.A., Pshinko, G.N., Puzyrnaya, L.N., and Kobets, S.A., J. Water Chem. and Technol., 2013, vol. 35, no. 3, pp. 104–111.
Pilipenko, A.T., Terletskaya, A.V., Bogoslovskaya, T.A., et al., Zhurn. Analit. Khimii, 1983, vol. 38, no. 5, pp. 807–810.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © G.N. Pshinko, V.M. Fedorova, S.A. Kobets, A.A. Kosorukov, 2016, published in Khimiya i Tekhnologiya Vody, 2016, Vol. 38, No. 2, pp. 140–149
About this article
Cite this article
Pshinko, G.N., Fedorova, V.M., Kobets, S.A. et al. The use of ferrocyanide Zn/Al-hydrotalcite for the sorptive concentration and radiometric determination of 137Cs in waters. J. Water Chem. Technol. 38, 77–82 (2016). https://doi.org/10.3103/S1063455X1602003X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1063455X1602003X