Abstract
A study is performed of the kinetics of triplet states of molecular nitrogen at the altitudes of Titan’s upper and middle atmosphere during the precipitation of high-energy electrons and cosmic rays. Collisional molecular processes with atmospheric components are considered for the first time in order to calculate concentrations of metastable molecular nitrogen \({{{\text{N}}}_{2}}\left( {{{{\text{A}}}^{3}}\Sigma _{u}^{ + }} \right)\). Numerical calculations show that inelastic molecular collisions result in the predominant accumulation of electronic excitation energy of metastable nitrogen at lower vibrational level ν = 0 and the altitudes of the middle atmosphere.
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REFERENCES
Campbell, L. and Brunger, M.J., Int. Rev. Phys. Chem., 2016, vol. 35, no. 2, p. 297.
Lebonnois, S., Bakes, E.L.O., and McKay, C.P., Icarus, 2002, vol. 159, no. 2, p. 505.
Wilson, E.H. and Atreya, S.K., J. Geophys. Res. Planets, 2004, vol. 109, no. 6, E06002.
Krasnopolsky, V.A., Planet. Space Sci., 2012, vol. 73, p. 318.
Vuitton, V., Dutuit, O., Smith, M., and Balucani, N., in Titan: Interior, Surface, Atmosphere and Space Environment, chap. 7, Cambridge: Cambridge Univ. Press, 2014, p. 224.
Szopa, C., Cernogora, G., Boufendi, L., et al., Planet. Space Sci., 2006, vol. 54, no. 4, p. 394.
Torokova, L., Watson, J., Krcma, F., et al., Contrib. Plasma Phys., 2015, vol. 55, no. 6, p. 470.
Pintassilgo, C.D. and Loureiro, J., Planet. Space Sci., 2009, vol. 57, no. 13, p. 1621.
Pintassilgo, C.D. and Loureiro, J., Adv. Space Res., 2010, vol. 46, no. 5, p. 657.
Jauberteau, J.L. and Jauberteau, I., J. Phys. D: Appl. Phys., 2018, vol. 51, no. 31, 315201.
Kirillov, A.S., Werner, R., and Guineva, V., Chem. Phys. Lett., 2017, vol. 685, p. 95.
Kirillov, A.S., Sol. Syst. Res., 2020, vol. 54, no. 1, p. 28.
Sharipov, A.S., Loukhovitski, B.I., and Starik, A.M., J. Phys. Chem. A, 2016, vol. 120, no. 25, p. 4349.
Umemoto, H., J. Chem. Phys., 2007, vol. 127, no. 1, 014304.
Gilmore, F.R., Laher, R.R., and Espy, P.J., J. Phys. Chem. Ref. Data, 1992, vol. 21, no. 5, p. 1005.
Kirillov, A.S., Ann. Geophys., 2008, vol. 26, no. 5, p. 1159.
Kirillov, A.S., Chem. Phys. Lett., 2016, vol. 643, p. 131.
Kirillov, A.S., Chem. Phys. Lett., 2019, vol. 715, p. 263.
Thomas, J.M., Jeffries, J.B., and Kaufman, F., Chem. Phys. Lett., 1983, vol. 102, no. 1, p. 50.
Golde, M.F., Ho, G.H., Tao, W., and Thomas, J.M., J. Phys. Chem., 1989, vol. 93, no. 3, p. 1112.
Slanger, T.G., Wood, B.J., and Black, G., J. Photochem., 1973, vol. 2, no. 1, p. 63.
Piper, L.G., J. Chem. Phys., 1992, vol. 97, no. 1, p. 270.
Umemoto, H., Phys. Chem. Chem. Phys., 2003, vol. 5, no. 24, p. 5392.
Bezard, B., Yelle, R.V., and Nixon, C.A., in Titan: Interior, Surface, Atmosphere and Space Environment, chap. 5, Cambridge: Cambridge Univ. Press, 2014, p. 158.
Vuitton, V., Yelle, R.V., Klippenstein, S.J., et al., Icarus, 2019, vol. 324, p. 120.
Herron, J.T., J. Phys. Chem. Ref. Data, 1999, vol. 28, no. 5, p. 1453.
Dreyer, J.W. and Perner, D., J. Chem. Phys., 1973, vol. 58, no. 3, p. 1195.
Kirillov, A.S., J. Atmos. Sol.-Terr. Phys., 2012, vols. 81–82, p. 9.
Landau, L.D., Sobranie trudov (Collection of Works), Moscow: Nauka, 1969, vol. 1.
Schwartz, R.N., Slawsky, Z.I., and Herzfeld, K.F., J. Chem. Phys., 1952, vol. 20, no. 10, p. 1591.
Nikitin, E.E., Teoriya elementarnykh atomno-molekulyarnykh protsessov v gazakh (Theory of Elementary Atomic and Molecular Processes in Gases), Moscow: Khimiya, 1970.
Nikitin, E.E. and Osipov, A.I., Itogi Nauki Tekh., Ser.: Kinet. Katal., vol. 4, Moscow: VINITI, 1977.
Nikitin, E.E., Osipov, A.I., and Umanskii, S.Ya., Khim. Plazmy, 1989, vol. 15, p. 3.
Kirillov, A.S., Kosm. Issled., 1997, vol. 35, no. 2, p. 155.
Kirillov, A.S., Ann. Geophys., 1998, vol. 16, no. 7, p. 838.
Millikan, R.C. and White, D.R., J. Chem. Phys., 1963, vol. 39, no. 12, p. 3209.
Billing, G.D. and Fisher, E.R., Chem. Phys., 1979, vol. 43, no. 3, p. 395.
Billing, G.D., Chem. Phys. Lett., 1980, vol. 76, no. 1, p. 178.
Herman, R.C. and Shuler, K.E., J. Chem. Phys., 1953, vol. 21, no. 2, p. 373.
Radtsig, A.A. and Smirnov, B.M., Spravochnik po atomnoi i molekulyarnoi fizike (Handbook of Atomic and Molecular Physics), Moscow: Atomizdat, 1980.
Cravens, T.E., Robertson, I.P., Clark, J., et al., Geophys. Rev. Lett., 2005, vol. 32, no. 12, L12108.
Agren, K., Wahlund, J.-E., Modolo, R., et al., Ann. Geophys., 2007, vol. 25, no. 11, p. 2359.
Molina-Cuberos, G.J., López-Moreno, J.J., Rodrigo, R., et al., Planet. Space Sci., 1999, vol. 47, nos 10–11, p. 1347.
Konovalov, V.P. and Son, E.E., Khim. Plazmy, 1987, vol. 14, p. 194.
Konovalov, V.P., Zh. Tekh. Fiz., 1993, vol. 63, no. 3, p. 23.
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Kirillov, A.S., Werner, R. & Guineva, V. Modeling Vibrational Populations of Metastable Molecular Nitrogen in Titan’s Atmosphere during the Precipitation of High-Energy Particles. Bull. Russ. Acad. Sci. Phys. 86, 335–342 (2022). https://doi.org/10.3103/S1062873822030108
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DOI: https://doi.org/10.3103/S1062873822030108